ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Bonding Situation of σ-E-H Complexes in Transition Metal and Main Group Compounds.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Heavier Alkyne-NiAngewandte Chemie (International ed. in English) · 2026Article
- 3-Center-3-Electron σ-Adduct Enables Silyl Radical Transfer below the Minimum Barrier for Silyl Radical Formation.Journal of the American Chemical Society · 2025Article
- Cross-Dehydrogenative Coupling of Secondary Amines with Silanes Catalyzed by Agostic Iridium-NSi Species.Inorganic chemistry · 2025Article
- σ-GeH and Germyl Cationic Pt(II) Complexes.Inorganic chemistry · 2022Article
- Bonding Situation of σ-E-H Complexes in Transition Metal and Main Group Compounds.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
The ambiguous bonding situation of σ-E-H (E=Si, B) complexes in transition metal compounds has been rationalized by means of Density Functional Theory calculations. To this end, the combination of the Energy Decomposition Analysis (EDA) method and its Natural Orbital for Chemical Valance (NOCV) extension has been applied to representative complexes described in the literature where the possible η
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