ArticleJournal of the American Chemical Society2022
Photooxidation of the Phenolate Anion is Accelerated at the Water/Air Interface.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Rubrene-Oxalate Electrochemiluminescence Reveals Physicochemical Properties of Triphasic Boundaries.Chemical & biomedical imaging · 2026Article
- Photoelectron imaging of substituted benzenes in aqueous aerosol droplets.Physical chemistry chemical physics : PCCP · 2026Article
- Molecular beam scattering of neon from flat jets of cold salty water.Chemical science · 2025Article
- Real-Time Visualization of an Elusive, Strong Reducing Agent during Tris(2,2'-bipyridyl)ruthenium(II) Electro-Oxidation in Water.Journal of the American Chemical Society · 2025Article
- Harnessing air-water interface to generate interfacial ROS for ultrafast environmental remediation.Nature communications · 2024Article
- Valence Electronic Structure of Interfacial Phenol in Water Droplets.The journal of physical chemistry. A · 2024Article
- Spectroscopy and dynamics of the hydrated electron at the water/air interface.Nature communications · 2024Article
- Pushing Photochemistry into Water: Acceleration of the Di-π-Methane Rearrangement and the Paternó-Büchi Reaction "On-Water".Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Molecular photodynamics can be dramatically affected at the water/air interface. Probing such dynamics is challenging, with product formation often probed indirectly through its interaction with interfacial water molecules using time-resolved and phase-sensitive vibrational sum-frequency generation (SFG). Here, the photoproduct formation of the phenolate anion at the water/air interface is probed directly using time-resolved electronic SFG and compared to transient absorption spectra in bulk water. The mechanisms are broadly similar, but 2 to 4 times faster at the surface. An additional decay is observed at the surface which can be assigned to either diffusion of hydrated electrons from the surface into the bulk or due to increased geminate recombination at the surface. These overall results are in stark contrast to phenol, where dynamics were observed to be 10
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