ArticleMolecules (Basel, Switzerland)2022
Intermolecular Interaction of Tetrabutylammonium and Tetrabutylphosphonium Salt Hydrates by Low-Frequency Raman Observation.
Article in Molecules (Basel, Switzerland), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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3 citing papers in PubMed.
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- Morphologies of Comb-like Polyacrylic Acid/Polyacrylate Copolymers as Functions of the Degree of Derivatization withPolymers · 2023Article
- Aquaphotomics-Exploring Water Molecular Systems in Nature.Molecules (Basel, Switzerland) · 2023Article
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5 authors.
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Abstract
Semi-clathrate hydrates are attractive heat storage materials because the equilibrium temperatures, located above 0 °C in most cases, can be changed by selecting guest cations and anions. The equilibrium temperatures are influenced by the size and hydrophilicity of guest ions, hydration number, crystal structure, and so on. This indicates that intermolecular and/or interionic interaction in the semi-clathrate hydrates may be related to the variation of the equilibrium temperatures. Therefore, intermolecular and/or interionic interaction in semi-clathrate hydrates with quaternary onium salts was directly observed using low-frequency Raman spectroscopy, a type of terahertz spectroscopy. The results show that Raman peak positions were mostly correlated with the equilibrium temperatures: in the semi-clathrate hydrates with higher equilibrium temperatures, Raman peaks around 65 cm
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