ArticleChemical science2022
Photoinduced inverse Sonogashira coupling reaction.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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Who cites it
6 citing papers in PubMed.
- Unlocking the Alkynyl Bromide Radical Anion With Alternating Current for Inverse Sonogashira C─H Coupling.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Homoleptic Bismuth Alkynes: Isolable Reagents for Selective Alkynyl Radical Transfer.Angewandte Chemie (International ed. in English) · 2026Article
- Alkynyl Radicals, Myths and Realities.JACS Au · 2025Review
- Photosensitized Reductive Elimination of Gold(III) to Enable Esterification of Aryl Iodides with Carboxylic Acids.JACS Au · 2024Article
- Base-assisted transmetalation enables gold-catalyzed oxidative Sonogashira coupling reaction.iScience · 2024Article
- Anaerobic photoinduced Cu(0/I)-mediated Glaser coupling in a radical pathway.Nature communications · 2023Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Alkynes are widely used in chemistry, medicine and materials science. Here we demonstrate a transition-metal and photocatalyst-free inverse Sonogashira coupling reaction between iodoalkynes and (hetero)arenes or alkenes under visible-light irradiation. Mechanistic and computational studies suggest that iodoalkynes can be directly activated by visible light irradiation, and an excited state iodoalkyne acted as an "alkynyl radical synthetic equivalent", reacting with a series of C(sp
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Registered trials
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