ArticlePhotochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology2022
Photochemical generation and characterization of the 5-endo-10,11-dihydrodibenzoazepine nitrenium ion.
Article in Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A photochemical precursor to the 5-endo-10,11-dihydroazepine nitrenium ion (1) was synthesized and used to characterize the intermediate by laser flash photolysis and stable product analysis. In addition, DFT calculations were carried out on the nitrenium ion. These results were compared with earlier studies on the diphenylnitrenium ion in order to ascertain the effect of the 2 carbon bridge on the reactions and properties of 1. It is shown that the geometric constraints provided by the bridging group (a) destabilize the triplet state of 1 relative to the singlet state (b) substantially increase the lifetime of 1 relative to Ph
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