ArticleScientific reports2022
Adsorption, thermodynamic, and quantum chemical investigations of an ionic liquid that inhibits corrosion of carbon steel in chloride solutions.
Article in Scientific reports, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
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- Isoniazid-derived ionic liquids for enhanced C-steels surface finishing via electrochemistry, supported by Monte Carlo, mechanistic study, theoretical, and docking methodology.Scientific reports · 2026Article
- Synthesis, Characterization, and Corrosion Inhibition Properties of a Novel Quaternary Ammonium Salt Containing Dual-Imidazoline Rings for N80 Carbon Steel Under COMaterials (Basel, Switzerland) · 2026Article
- Insight into the time-dependent corrosion protection of mild steel by green ionic liquids: a combined electrochemical, surface, and computational study.RSC advances · 2025Article
- Understanding soil factors in corrosion and conservation of buried bronze statuettes: insights for preservation strategies.Scientific reports · 2024Article
- An electrochemical, and surface studies of synthesized Gemini ionic liquid as corrosion inhibitor for carbon steel in petroleum field.Scientific reports · 2024Article
- Flawless polyaniline coating for preservation and corrosion protection of ancient steel spearheads: an archaeological study from military museum, Al-Qala, Egypt.Scientific reports · 2024Article
- Investigation of olive leaf extract as a potential environmentally-friendly corrosion inhibitor for carbon steel.Scientific reports · 2023Article
- Sustainable development of an effective anti-corrosion film over the St12-steel surface against seawater attacks using Ce(III) ions/tri-sodium phosphate anions.Scientific reports · 2023Article
- Preparation of Chitosan/β-Cyclodextrin Composite Membrane and Its Adsorption Mechanism for Proteins.Molecules (Basel, Switzerland) · 2023Article
- Vicia faba peel extracts bearing fatty acids moieties as a cost-effective and green corrosion inhibitor for mild steel in marine water: computational and electrochemical studies.Scientific reports · 2022Article
Corrections and comments
- Erratum issued
- Erratum issued
Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The purpose of this work lies in the use of ionic liquids as corrosion inhibitors due to the difficulty in some oil fields with the solubility of corrosion inhibitors and these materials can be miscible with water and thus provide a solution to such problems in the industry. The second purpose is concerned with the lower toxicity of these compounds compared with the most common corrosion inhibitors. The study covered the corrosion inhibition performance of the ionic liquid 1-butyl-3-methylimidazolium trifluoromethyl sulfonate ([BMIm]TfO) for carbon steel in 3.5% NaCl solutions. The study comprised electrochemical, adsorption, and quantum chemical investigations. The results manifested that [BMIm]TfO can be considered a promising corrosion inhibitor and the inhibition efficacy intensifies as the concentration rises. The observed inhibitive effect can be correlated to the adsorption of the ionic liquid species and the creation of protecting films on the surface. The mode of adsorption follows the Langmuir adsorption isotherm. The polarization results showed that the ionic liquid [BMIm]TfO functions as a mixed inhibitor. Reliance of the corrosion influence on the temperature in the existence and absence of [BMIm]TfO was demonstrated in the temperature range of 303-333 K using polarization data. Activation parameters were determined and discussed. The observed inhibition performance of [BMIm]TfO was correlated with the electronic properties of the ionic liquid using a quantum chemical study.
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