Evidence map›Paper›PMID 35867912›Full record

ArticleThe journal of physical chemistry. B2022

Aprotic Solvent Accumulation Amplifies Ion Current Rectification in Conical Nanopores.

Emer B Farrell, Dominik Duleba, Robert P Johnson

Abstract read
In one paragraph

Article in The journal of physical chemistry. B, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Emer B FarrellSchool of Chemistry, University College Dublin, Belfield, Dublin 4 D04 V1W8, Ireland.
Dominik DulebaSchool of Chemistry, University College Dublin, Belfield, Dublin 4 D04 V1W8, Ireland.ORCID 0000-0002-0618-2162
Robert P JohnsonSchool of Chemistry, University College Dublin, Belfield, Dublin 4 D04 V1W8, Ireland.ORCID 0000-0002-8046-2138

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Ion current rectification is highly reported in aqueous electrochemical systems and sensors but lacks exploration in organic systems due to the additional complexity introduced by non-aqueous solvents. Herein, a detailed study on ion current rectification with highly polar and mildly polar aprotic organic solvents as a function of tetraethylammonium tetrafluoroborate supporting electrolyte concentration is presented. To explain our experimental results, we introduce a previously unreported phenomenon: the formation of a double-junction diode within the nanopore that arises due to a complex interplay between ion and solvent enrichment effects. Finite element simulations are used to explore this phenomenon and the subsequent effect on the rectifying behavior of conical quartz nanopores.

Indexed as

NanoporesElectrolytesIon TransportSolventsElectrolytesSolvents

Identifiers

PMID35867912
PMCPMC9358645

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.