ArticleThe journal of physical chemistry letters2022
Accurate Vertical Ionization Energy of Water and Retrieval of True Ultraviolet Photoelectron Spectra of Aqueous Solutions.
Article in The journal of physical chemistry letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Liquid-Microjet Photoelectron Spectroscopy of the Photoactive Yellow Protein Chromophore in Aqueous Solution.The journal of physical chemistry. A · 2026Article
- Photoelectron imaging of substituted benzenes in aqueous aerosol droplets.Physical chemistry chemical physics : PCCP · 2026Article
- Retrieval of Genuine Ultraviolet Liquid-Microjet Photoelectron Spectra.The journal of physical chemistry. A · 2025Article
- Low-Energy Photoelectron Spectroscopy and Scattering from Aqueous Solutions and the Role of Solute Surface Activity.Journal of the American Chemical Society · 2025Article
- Valence Electronic Structure of Interfacial Phenol in Water Droplets.The journal of physical chemistry. A · 2024Article
- Wavelength dependent mechanism of phenolate photooxidation in aqueous solution.Chemical science · 2023Article
- UV Photoelectron Spectroscopy of Aqueous Solutions.Accounts of chemical research · 2022Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Ultraviolet (UV) photoelectron spectroscopy provides a direct way of measuring valence electronic structure; however, its application to aqueous solutions has been hampered by a lack of quantitative understanding of how inelastic scattering of low-energy (<5 eV) electrons in liquid water distorts the measured electron kinetic energy distributions. Here, we present an efficient and widely applicable method for retrieving true UV photoelectron spectra of aqueous solutions. Our method combines Monte Carlo simulations of electron scattering and spectral inversion, with molecular dynamics simulations of depth profiles of organic solutes in aqueous solution. Its application is demonstrated for both liquid water, and aqueous solutions of phenol and phenolate, which are ubiquitous biologically relevant structural motifs.
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Registered trials
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