Evidence map›Paper›PMID 35862831›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022

Controlling Electronic Events Through Rational Structural Design in Subphthalocyanine-Corrole Dyads: Synthesis, Characterization, and Photophysical Properties.

Víctor Mariñas, Benedikt Platzer, Jorge Labella, Fabrizio Caroleo, Sara Nardis, Roberto Paolesse, Dirk M Guldi, Tomás Torres

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Víctor MariñasDepartment of Chemical Science and Technologies, University of Rome Tor Vergata, Via della Ricerca Scientifica, 00133, Rome, Italy.
Benedikt PlatzerDepartment of Chemistry and Pharmacy, Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058, Erlangen, Germany.
Jorge LabellaDepartment of Organic Chemistry, Universidad Autónoma de Madrid, Campus de Cantoblanco, C/ Francisco Tomás y Valiente 7, 28049, Madrid, Spain.ORCID http://orcid.org/0000-0001-5665-2778
Fabrizio CaroleoDepartment of Chemical Science and Technologies, University of Rome Tor Vergata, Via della Ricerca Scientifica, 00133, Rome, Italy.
Sara NardisDepartment of Chemical Science and Technologies, University of Rome Tor Vergata, Via della Ricerca Scientifica, 00133, Rome, Italy.
Roberto PaolesseDepartment of Chemical Science and Technologies, University of Rome Tor Vergata, Via della Ricerca Scientifica, 00133, Rome, Italy.
Dirk M GuldiDepartment of Chemistry and Pharmacy, Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058, Erlangen, Germany.
Tomás TorresDepartment of Organic Chemistry, Universidad Autónoma de Madrid, Campus de Cantoblanco, C/ Francisco Tomás y Valiente 7, 28049, Madrid, Spain.ORCID http://orcid.org/0000-0001-9335-6935

Funding

MINECO PID2020- 116490GB I00MINECO SEV-2016-0686PRIN MIUR 2017EKCS35_002
6 · The paper itself

Abstract

Porphyrinoids are considered perfect candidates for their incorporation into electron donor-acceptor (D-A) arrays due to their remarkable optoelectronic properties and low reorganization energies. For the first time, a series of subphthalocyanine (SubPc) and corrole (Cor) were covalently connected through a short-range linkage. SubPc axial substitution strategies were employed, which allowed the synthesis of the target molecules in decent yields. In this context, a qualitative synthetic approach was performed to reverse the expected direction of the different electronic events. Consequently, in-depth absorption, fluorescence, and electrochemical assays enabled the study of electronic and photophysical properties. Charge separation was observed in cases of electron-donating Cors, whereas a quantitative energy transfer from the Cor to the SubPc was detected in the case of electron accepting Cors.

Indexed as

PorphyrinsElectronicsElectronsEnergy TransfercorrolePorphyrinscorroleselectron transferorganic photovoltaicsporphyrinoidssubphthalocyanines

Identifiers

PMID35862831
PMCPMC9804354

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.