ArticleProceedings of the National Academy of Sciences of the United States of America2022
Chirality enhances oxygen reduction.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
What it found
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Who cites it
28 citing papers in PubMed.
- Chiral Bifacial Indacenodithiophene-Based Hole-Transport Materials With Chirality-Induced Spin Selectivity: Chirality-Spin Polarity Correspondence and Perovskite Passivation.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Chiral N-Heterocyclic Carbene On-Surface Induced Electronic Spin Filtration.Journal of the American Chemical Society · 2026Article
- Atomic-scale engineering of Pt shells on chiral Au nanoparticles for enhanced oxygen reduction.Nature communications · 2026Article
- Multilevel Strategies for Oxygen Electrocatalysis From Interfacial Environment to Spin Modulation.Chemical record (New York, N.Y.) · 2026Review
- Chiral-Encoded Pt-Ir Surfaces as Apparent Spin Filter for Enhanced Oxygen Reduction.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Chirality-promoted photocatalysis: a strategic framework for advancing future dye degradation technologies.RSC advances · 2026Article
- What Does It Take for an Organic Closed Shell Molecule to Become Magnetic?The journal of physical chemistry letters · 2025Review
- Synergistic Spin-Mediated Catalysis for the Oxygen Evolution Reaction.Journal of the American Chemical Society · 2025Article
- Article
- Sevoflurane and Desflurane Spin-Decoherence Effect on Fe(III)acetylacetonate Redox Process.Molecules (Basel, Switzerland) · 2025Article
- Supramolecular chirality largely modulates chemical doping of conjugated polymers.Nature communications · 2025Article
- Nanoarchitectonics for Pentagon Defects in Carbon: Properties and Catalytic Role in Oxygen Reduction Reaction.Small methods · 2025Review
- Chiral Induced Spin Polarized Electron Current: Origin of the Chiral Induced Spin Selectivity Effect.The journal of physical chemistry letters · 2025Article
- Decoupling Activity and Specificity in Coronazymes.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Elucidating the Chirality-Induced Spin Selectivity Effect of Co-Doped NiO Deposited on Ni Foam for Highly Stable Zn-Air Batteries.ACS applied materials & interfaces · 2025Article
- Direct control of electron spin at an intrinsically chiral surface for highly efficient oxygen reduction reaction.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- Chiral Phonons Enhance Ferromagnetism.The journal of physical chemistry letters · 2025Article
- Improved Catalyst Performance for the Oxygen Evolution Reaction under a Chiral Bias.ACS catalysis · 2024Article
- The chirality-induced spin selectivity effect in asymmetric spin transport: from solution to device applications.Chemical science · 2024Review
- A chemical perspective on the chiral induced spin selectivity effect.National science review · 2024Review
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Controlled reduction of oxygen is important for developing clean energy technologies, such as fuel cells, and is vital to the existence of aerobic organisms. The process starts with oxygen in a triplet ground state and ends with products that are all in singlet states. Hence, spin constraints in the oxygen reduction must be considered. Here, we show that the electron transfer efficiency from chiral electrodes to oxygen (oxygen reduction reaction) is enhanced over that from achiral electrodes. We demonstrate lower overpotentials and higher current densities for chiral catalysts versus achiral ones. This finding holds even for electrodes composed of heavy metals with large spin-orbit coupling. The effect results from the spin selectivity conferred on the electron current by the chiral assemblies, the chiral-induced spin selectivity effect.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.