Evidence map›Paper›PMID 35856293›Full record

ArticleAngewandte Chemie (International ed. in English)2022

Circularly Polarized Luminescence in a Möbius Helicene Carbon Nanohoop.

Juraj Malinčík, Sudhakar Gaikwad, Juan P Mora-Fuentes, Marc-Aurèle Boillat, Alessandro Prescimone, Daniel Häussinger, Araceli G Campaña, Tomáš Šolomek

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.

0numbers the graph read from it
0cells of the map it votes in
17citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

17 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Article
  6. Synthesis of Enantiopure [3]Cyclorubicenes.Angewandte Chemie (International ed. in English) · 2026
    Article
  7. Article
  8. Size and Geometry Impact the Chiroptical Properties of Double Nanohoops.Journal of the American Chemical Society · 2025
    Article
  9. Review
  10. Article
  11. A Writhed Möbius Nanobelt Derived from [7]Helicene.Journal of the American Chemical Society · 2025
    Article
  12. Article
  13. Article
  14. Article
  15. Review
  16. Article
  17. Circularly Polarized Luminescence in a Möbius Helicene Carbon Nanohoop.Angewandte Chemie (International ed. in English) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Juraj MalinčíkDepartment of Chemistry, University of Basel, St. Johann's-Ring 19, 4056, Basel, Switzerland.ORCID 0000-0002-5633-2755
Sudhakar GaikwadDepartment of Chemistry, University of Basel, St. Johann's-Ring 19, 4056, Basel, Switzerland.ORCID 0000-0002-0093-6963
Juan P Mora-FuentesDepartment of Organic Chemistry, University of Granada, Avda Fuentenueva, s/n, 18 071, Granada, Spain.
Marc-Aurèle BoillatDepartment of Chemistry, University of Basel, St. Johann's-Ring 19, 4056, Basel, Switzerland.
Alessandro PrescimoneDepartment of Chemistry, University of Basel, St. Johann's-Ring 19, 4056, Basel, Switzerland.ORCID 0000-0002-3631-5210
Daniel HäussingerDepartment of Chemistry, University of Basel, St. Johann's-Ring 19, 4056, Basel, Switzerland.ORCID 0000-0002-4798-0072
Araceli G CampañaDepartment of Organic Chemistry, University of Granada, Avda Fuentenueva, s/n, 18 071, Granada, Spain.ORCID 0000-0001-5483-5642
Tomáš ŠolomekDepartment of Chemistry, University of Basel, St. Johann's-Ring 19, 4056, Basel, Switzerland.ORCID 0000-0003-0013-4116

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We present the first helicene carbon nanoohop that integrates a [6]helicene into [7]cycloparaphenylene. The [6]helicene endows the helicene carbon nanohoop with chiroptical properties and configurational stability typical for higher helicenes, while the radially conjugated seven para-phenylenes largely determine the optoelectronic properties. The structure of the helicene carbon nanoohop was unambiguously characterized by NMR, MS and X-ray analysis that revealed that it possesses a topology of a Möbius strip in the solid state and in solution. The chirality transfers from the [6]helicene to the para-phenylenes and leads to a pronounced circular dichroism and bright circularly polarized luminescence, which is affected by the structural topology of the nanohoop.

Indexed as

LuminescencePolycyclic CompoundsCarbonStereoisomerismCarbonhelicenesPolycyclic CompoundsChiralityCircularly Polarized LuminescenceCycloparaphenylenesHelicenesMöbius TopologyMolecular Nanocarbons

Identifiers

PMID35856293
PMCPMC9543836

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.