Evidence map›Paper›PMID 35844638›Full record

ArticleFrontiers in chemistry2022

A Comparative Study of Biomimetic Synthesis of EDOT-Pyrrole and EDOT-Aniline Copolymers by Peroxidase-like Catalysts: Towards Tunable Semiconductive Organic Materials.

Manuel Eduardo Martínez-Cartagena, Juan Bernal-Martínez, Arnulfo Banda-Villanueva, Ilse Magaña, Teresa Córdova, Antonio Ledezma-Pérez, Salvador Fernández-Tavizón, Ramón Díaz de León

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Article in Frontiers in chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

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2citing papers in PubMed
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2 · The registry

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3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

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4 · The record

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5 · Who and what money

Authors and funding

8 authors.

Manuel Eduardo Martínez-CartagenaAdvanced Materials Department, Research Center in Applied Chemistry (CIQA), Saltillo, México.
Juan Bernal-MartínezLaboratory in Biomedicine and Nanotechnology, Aguascalientes, México.
Arnulfo Banda-VillanuevaPolymerization Processes Department, Research Center in Applied Chemistry (CIQA), Saltillo, México.
Ilse MagañaPolymerization Processes Department, Research Center in Applied Chemistry (CIQA), Saltillo, México.
Teresa CórdovaPolymerization Processes Department, Research Center in Applied Chemistry (CIQA), Saltillo, México.
Antonio Ledezma-PérezAdvanced Materials Department, Research Center in Applied Chemistry (CIQA), Saltillo, México.
Salvador Fernández-TavizónAdvanced Materials Department, Research Center in Applied Chemistry (CIQA), Saltillo, México.
Ramón Díaz de LeónPolymerization Processes Department, Research Center in Applied Chemistry (CIQA), Saltillo, México.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

It has been two decades since biomimetic synthesis of conducting polymers were first reported, however, the systematic investigation of how catalysts influence the properties of the conducting polymers has not been reported yet. In this paper, we report a comparative study between peroxidase-like catalyst, dopants, and their effect on the properties of poly (3,4-ethylenedioxythiophene) (PEDOT), polypyrrole (PPY), and polyaniline (PANI). We also investigate the EDOT-Pyrrole and EDOT-Aniline copolymerization by enzymomimetic synthesis using two catalysts (Ferrocene and Hematin). It was found that, chemically, there are no detectable effects, only having small contributions in molar ratios greater than 0.7-0.3. Spectroscopic data provide solid evidence concerning the effect in the variation of the molar fractions, finding that, as the molar fraction of EDOT decreases, changes associated with loss of the conjugation of the structure and the oxidation state of the chains were observed. The electrical conductivity was considerably modified depending on the type of catalyst. Hematin produces conductive homopolymers and copolymers when doped with

Indexed as

Biomimeticconjugated semiconductive copolymerpoly (3,4ethylenedioxythiophene)PolyanilinePolypyrrole

Identifiers

PMID35844638
PMCPMC9278020

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