ArticleNational science review2022
Unprecedented strong and reversible atomic orbital hybridization enables a highly stable Li-S battery.
Article in National science review, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 33 citations in OpenAlex.
- CuS-Cobalt Porphyrin Organic-Inorganic Heterojunction with a Long-Lived Charge-Separated State for Efficient COAdvanced materials (Deerfield Beach, Fla.) · 2026Article
- Breaking energy-power-stability trade-off in Li-S battery via HoMS.National science review · 2026Article
- Unlocking high-voltage anode-free sodium-sulfur batteries.National science review · 2026Article
- Magnetic-field-guided catalytic effect mitigates LiNational science review · 2026Article
- p-d orbital hybridization induced by transition metal atom sites for room-temperature sodium-sulfur batteries.National science review · 2025Article
- Rekindling hopes for lithium-sulfur batteries.National science review · 2025Article
Corrections and comments
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Authors and funding
7 authors at 4 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The shuttle effect and excessive volume change of the sulfur cathode severely impede the industrial implementation of Li-S batteries. It is still highly challenging to find an efficient way to suppress the shuttle effect and volume expansion. Here, we report, for the first time, an innovative atomic orbital hybridization concept to construct the hierarchical hollow sandwiched sulfur nanospheres with double-polyaniline layers as the cathode material for large-scale high-performance Li-S batteries. This hierarchically 3D, cross-linked and stable sulfur-polyaniline backbone with interconnected disulfide bonds provides a new type and strong intrinsic chemical confinement of sulfur owing to the atomic orbital hybridization of Li 2s, S 3p, C 2p and N 2p. Crucially, such atomic orbital hybridization of sulfur sandwiched in the double sulfur-polyaniline network is highly reversible during the discharge/charge process and can very efficiently suppress the shuttle effect and volume expansion, contributing to a very high capacity of 1142 mAh g
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