Evidence map›Paper›PMID 35818987›Full record

ArticleAngewandte Chemie (International ed. in English)2022

The Highest Oxidation State of Rhodium: Rhodium(VII) in [RhO

Mayara da Silva Santos, Tony Stüker, Max Flach, Olesya S Ablyasova, Martin Timm, Bernd von Issendorff, Konstantin Hirsch, Vicente Zamudio-Bayer, Sebastian Riedel, J Tobias Lau

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Review
  2. Article
  3. Platform Design Enabling Silver(III) Stabilization ─ The Uprise of AgChemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Review
  4. Article
  5. The Highest Oxidation State of Rhodium: Rhodium(VII) in [RhOAngewandte Chemie (International ed. in English) · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Mayara da Silva SantosPhysikalisches Institut, Albert-Ludwigs-Universität Freiburg, Hermann-Herder-Straße 3, 79104, Freiburg, Germany.ORCID http://orcid.org/0000-0003-4439-6441
Tony StükerInstitut für Chemie und Biochemie-Anorganische Chemie, Freie Universität Berlin, Fabeckstraße 34/36, 14195, Berlin, Germany.ORCID http://orcid.org/0000-0002-6161-3586
Max FlachPhysikalisches Institut, Albert-Ludwigs-Universität Freiburg, Hermann-Herder-Straße 3, 79104, Freiburg, Germany.
Olesya S AblyasovaPhysikalisches Institut, Albert-Ludwigs-Universität Freiburg, Hermann-Herder-Straße 3, 79104, Freiburg, Germany.
Martin TimmAbteilung für Hochempfindliche Röntgenspektroskopie, Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Straße 15, 12489, Berlin, Germany.ORCID http://orcid.org/0000-0003-4901-203X
Bernd von IssendorffPhysikalisches Institut, Albert-Ludwigs-Universität Freiburg, Hermann-Herder-Straße 3, 79104, Freiburg, Germany.ORCID http://orcid.org/0000-0002-4358-4494
Konstantin HirschAbteilung für Hochempfindliche Röntgenspektroskopie, Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Straße 15, 12489, Berlin, Germany.ORCID http://orcid.org/0000-0001-5050-3026
Vicente Zamudio-BayerAbteilung für Hochempfindliche Röntgenspektroskopie, Helmholtz-Zentrum Berlin für Materialien und Energie, Albert-Einstein-Straße 15, 12489, Berlin, Germany.ORCID http://orcid.org/0000-0002-4038-0584
Sebastian RiedelInstitut für Chemie und Biochemie-Anorganische Chemie, Freie Universität Berlin, Fabeckstraße 34/36, 14195, Berlin, Germany.ORCID http://orcid.org/0000-0003-4552-5719
J Tobias LauPhysikalisches Institut, Albert-Ludwigs-Universität Freiburg, Hermann-Herder-Straße 3, 79104, Freiburg, Germany.ORCID http://orcid.org/0000-0003-0976-6902

Funding

Bundesministerium für Bildung und Forschung, BMBF BMBF-05K16VF1Deutsche Forschungsgemeinschaft, DFG GRK 2717, Dynamics of Controlled Atomic and Molecular SystemsEuropean Research Council, ERC HighPotOx (818862)
6 · The paper itself

Abstract

Although the highest possible oxidation states of all transition elements are rare, they are not only of fundamental interest but also relevant as potentially strong oxidizing agents. In general, the highest oxidation states are found in the electron-rich late transition elements of groups 7-9 of the periodic table. Rhodium is the first element of the 4d transition metal series for which the highest known oxidation state does not equal its group number of 9, but reaches only a significantly lower value of +6 in exceptional cases. Higher oxidation states of rhodium have remained elusive so far. In a combined mass spectrometry, X-ray absorption spectroscopy, and quantum-chemical study of gas-phase

Indexed as

Gas PhaseOxidation StateOxidesRhodiumX-Ray Absorption Spectroscopy

Identifiers

PMID35818987
PMCPMC9544489

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.