ArticleNature communications2022
Chiral self-sorting and guest recognition of porous aromatic cages.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed.
- Porous organic cage mixed matrix membranes for efficient enantioseparation.Nature communications · 2025Article
- Tautomerism-Coupled Self-Assembly and Transformations of Iminopyrrole Metallacages.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Homochiral Self-Sorting During Macrocycle Formation and their Chiroptical Properties.ChemistryOpen · 2025Article
- Chiral covalent organic cages: Construction and chiral functions.Smart molecules : open access · 2025Review
- [Applications of ordered porous materials in chromatography separation and analysis].Se pu = Chinese journal of chromatography · 2025Article
- Social Self-Sorting of Quasi-Racemates: A Unique Approach for Dual-Pore Molecular Crystals.Journal of the American Chemical Society · 2024Article
- Stereocontrolled Self-Assembly of a Helicate-Bridged CuJournal of the American Chemical Society · 2024Article
- [Research progress of stationary phase of gas chromatography based on chiral organic frameworks].Se pu = Chinese journal of chromatography · 2024Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
The synthesis of ultra-stable chiral porous organic cages (POCs) and their controllable chiral self-sorting at the molecular and supramolecular level remains challening. Herein, we report the design and synthesis of a serial of axially chiral porous aromatic cages (PAC 1-S and 1-R) with high chemical stability. The theoretical and experimental studies on the chiral self-sorting reveal that the exclusive self-recognition on cage formation is an enthalpy-driven process while the chiral narcissistic and self-sorting on supramolecular assembly of racemic cages can be precisely regulated by π-π and C-H…π interactions from different solvents. Regarding the chemical stability, the crystallinity of PAC 1 is maintained in aqueous solvents, such as boiling water, high-concentrated acid and alkali; mixtures of solvents, such as 1 M H
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Registered trials
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