ArticleLangmuir : the ACS journal of surfaces and colloids2022
Effects of High Gamma Doses on the Structural Stability of Metal-Organic Frameworks.
Article in Langmuir : the ACS journal of surfaces and colloids, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Radiation-Resistant Kr-Selective MOF With Record Kr/Xe Selectivity at Elevated Pressure.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Giant Isotope Effect in Metal-Organic Frameworks Boosts Unprecedented Photo- and Radio-Luminescence Enhancement.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Interplay between noble gases and MOFs: Insights fromScience advances · 2025Article
- Effects of Ionizing Radiation on Halogen-Bonded Dipyridyl-Naphthalenediimide Cocrystals.Crystal growth & design · 2025Article
- Exploring the Gamma-Ray Enhanced NIR-Luminescence and Cytotoxic Potential of Lanthanide-Naphthalene Dicarboxylate based Metal-Organic Frameworks.Journal of fluorescence · 2025Article
- Effects of Gamma Radiation on Single- and Multicomponent Organic Crystalline Materials.Crystal growth & design · 2023Article
- Article
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Authors and funding
5 authors.
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Abstract
Four different MOFs were exposed to γ rays by a cobalt-60 source reaching a maximum dose of 5 MGy. The results showed that the MIL-100 (Cr) and MIL-100 (Fe) did not exhibit obvious structural damage, suggesting their excellent radiation stability. MIL-101 (Cr) showed good radiation stability up to 4 MGy, but its structure started degrading with increasing radiation dose. Furthermore, the results showed that the structure of AlFu MOFs started to decompose at a gamma dose of 1 MGy, exhibiting a much lower tolerance to γ radiation. At this radiation energy, the dominant interaction of the gamma-ray with MOFs is the Compton effect and the radiation stability of MOFs can be improved by prolific aromatic linkers, high linker connectivity, and good crystallinity. The results of this study indicate that MIL-100 and MIL-101 MOFs have a good potential to be employed in nuclear applications, where relatively high radiation doses play a role, for example, nuclear waste treatment and radionuclides production.
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Registered trials
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