Evidence map›Paper›PMID 35816010›Full record

ReviewChemistry, an Asian journal2022

Polythioesters Prepared by Ring-Opening Polymerization of Cyclic Thioesters and Related Monomers.

Hui Li, Sophie M Guillaume, Jean-François Carpentier

Open access · hybridAbstract readReview
In one paragraph

Review in Chemistry, an Asian journal, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
4.3field-weighted citation impact, top 5% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed, 58 citations in OpenAlex.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors at 1 institution in 1 country.

Hui LiUniv Rennes, CNRS, ISCR-UMR 6226, 35000, Rennes, France.
Sophie M GuillaumeUniv Rennes, CNRS, ISCR-UMR 6226, 35000, Rennes, France.ORCID http://orcid.org/0000-0003-2917-8657
Jean-François CarpentierUniv Rennes, CNRS, ISCR-UMR 6226, 35000, Rennes, France.ORCID http://orcid.org/0000-0002-9160-7662
Centre National de la Recherche Scientifique · FR

Funding

China Scholarship Council 201804910783
6 · The paper itself

Abstract

Polyhydroxyalkanoates (PHAs) are biodegradable and biocompatible polyesters with a wide range of applications; in particular, they currently stand as promising alternatives to conventional polyolefin-based "plastics". The introduction of sulfur atoms within the PHAs backbone can endow the resulting polythioesters (PTEs) with differentiated, sometimes enhanced thermal, optical and mechanical properties, thereby widening their versatility and use. Hence, PTEs have been gaining increasing attention over the past half-decade. This review highlights recent advances towards the synthesis of well-defined PTEs by ring-opening polymerization (ROP) of cyclic thioesters - namely thiolactones - as well as of S-carboxyanhydrides and thionolactones; it also covers the ring-opening copolymerization (ROCOP) of cyclic thioanhydrides or thiolactones with epoxides or episulfides. Most of the ROP reactions described are of anionic type, mediated by inorganic, organic or organometallic initiators/catalysts, along with a few enzymatic reactions as well. Emphasis is placed on the reactivity of the thio monomers, in relation to their ring-size ranging from 4- to 5-, 6- and 7-membered cycles, the nature of the catalyst/initiating systems implemented and their efficiency in terms of activity and control over the PTE molar mass, dispersity, topology, and microstructure.

Indexed as

PolyestersCatalysisMolecular WeightPolymerizationPolyestersDegradabilityPolythioesterRecyclabilityRing-Opening Copolymerization (ROCOP)Ring-Opening Polymerization (ROP)ThioesterThiolactone

Identifiers

PMID35816010
PMCPMC9543045
OpenAlexW4285011716

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.