Evidence map›Paper›PMID 35808964›Full record

ReviewAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2022

Homogeneity of Supported Single-Atom Active Sites Boosting the Selective Catalytic Transformations.

Yujie Shi, Yuwei Zhou, Yang Lou, Zupeng Chen, Haifeng Xiong, Yongfa Zhu

Abstract readReview
In one paragraph

Review in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.

0numbers the graph read from it
0cells of the map it votes in
16citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

16 citing papers in PubMed.

  1. Review
  2. Review
  3. Rational design of CiScience · 2026
    Review
  4. Article
  5. Boosting Hydrogenation of COAngewandte Chemie (International ed. in English) · 2025
    Article
  6. Single Atom Cocatalysts in Photocatalysis.Advanced materials (Deerfield Beach, Fla.) · 2025
    Review
  7. Review
  8. Article
  9. Article
  10. Article
  11. Article
  12. Article
  13. Review
  14. Review
  15. Pd/δ-MnOFrontiers in chemistry · 2022
    Article
  16. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Yujie ShiKey Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, 214122, P. R. China.
Yuwei ZhouKey Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, 214122, P. R. China.
Yang LouKey Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu, 214122, P. R. China.ORCID https://orcid.org/0000-0002-8310-8150
Zupeng ChenCollege of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, P. R. China.
Haifeng XiongCollege of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, P. R. China.
Yongfa ZhuDepartment of Chemistry, Tsinghua University, Beijing, 100084, P. R. China.

Funding

Fundamental Research Funds for the Central Universities JUSRP11905Jiangsu Specially-Appointed Professor 1046010241211400National High-Level Young Talents ProgramNational Key R&D Program of China 2021YFB3501900National Natural Science Foundation of China 21908079National Natural Science Foundation of China 22072118National Natural Science Foundation of China U21A20326Natural Science Foundation of Jiangsu Province BK20211239Science and Technology Projects of Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM)(HRTP-[2022]-3)State Key Laboratory of Fine Chemicals, Dalian University of Technology KF2005
6 · The paper itself

Abstract

Selective conversion of specific functional groups to desired products is highly important but still challenging in industrial catalytic processes. The adsorption state of surface species is the key factor in modulating the conversion of functional groups, which is correspondingly determined by the uniformity of active sites. However, the non-identical number of metal atoms, geometric shape, and morphology of conventional nanometer-sized metal particles/clusters normally lead to the non-uniform active sites with diverse geometric configurations and local coordination environments, which causes the distinct adsorption states of surface species. Hence, it is highly desired to modulate the homogeneity of the active sites so that the catalytic transformations can be better confined to the desired direction. In this review, the construction strategies and characterization techniques of the uniform active sites that are atomically dispersed on various supports are examined. In particular, their unique behavior in boosting the catalytic performance in various chemical transformations is discussed, including selective hydrogenation, selective oxidation, Suzuki coupling, and other catalytic reactions. In addition, the dynamic evolution of the active sites under reaction conditions and the industrial utilization of the single-atom catalysts are highlighted. Finally, the current challenges and frontiers are identified, and the perspectives on this flourishing field is provided.

Indexed as

active sitechemical transformationshomogeneityselectivitysingle-atom catalyst

Identifiers

PMID35808964
PMCPMC9404403

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.