ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Temperature Driven Transformation of the Flexible Metal-Organic Framework DUT-8(Ni).
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed, 19 citations in OpenAlex.
- Zero- to One-Dimensional Transformation in a Highly Porous Metal-Organic Framework to Enhance Physicochemical Properties.Journal of the American Chemical Society · 2025Article
- A Critical Assessment on Calculating Vibrational Spectra in Nanostructured Materials.Journal of chemical theory and computation · 2024Review
- A Series of Novel 3D Coordination Polymers Based on the Quinoline-2,4-dicarboxylate Building Block and Lanthanide(III) Ions-Temperature Dependence Investigations.Molecules (Basel, Switzerland) · 2023Article
- Selective sorption of oxygen and nitrous oxide by an electron donor-incorporated flexible coordination network.Communications chemistry · 2023Article
- Temperature Driven Transformation of the Flexible Metal-Organic Framework DUT-8(Ni).Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
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Authors and funding
15 authors at 8 institutions in 6 countries.
Funding
Abstract
DUT-8(Ni) metal-organic framework (MOF) belongs to the family of flexible pillared layer materials. The desolvated framework can be obtained in the open pore form (op) or in the closed pore form (cp), depending on the crystal size regime. In the present work, we report on the behaviour of desolvated DUT-8(Ni) at elevated temperatures. For both, op and cp variants, heating causes a structural transition, leading to a new, crystalline compound, containing two interpenetrated networks. The state of the framework before transition (op vs. cp) influences the transition temperature: the small particles of the op phase transform at significantly lower temperature in comparison to the macroparticles of the cp phase, transforming close to the decomposition temperature. The new compound, confined closed pore phase (ccp), was characterized by powder X-ray diffraction and spectroscopic techniques, such as IR, EXAFS, and positron annihilation lifetime spectroscopy (PALS). Thermal effects of structural transitions were studied using differential scanning calorimetry (DSC), showing an overall exothermic effect of the process, involving bond breaking and reformation. Theoretical calculations reveal the energetics, driving the observed temperature induced phase transition.
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