ArticleChemical science2022
Isolable acetylene complexes of copper and silver.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 21 citations in OpenAlex.
- An Axially Chiral Pyridyno-allenophane in a 2:1 Edge-to-Face Silver(I) Sandwich Complex: Synthesis and Structural Characterization.ACS organic & inorganic Au · 2026Article
- Switchable supramolecular polymers of a Pt(II) complexRSC advances · 2025Article
- Heteronuclear Complexes Containing Pt(II) and Ag(I) Centers: Application to Efficient Light-Emitting Electrochemical Cells.ACS applied materials & interfaces · 2025Article
- Water-catalyzed iron-molybdenum carbyne formation in bimetallic acetylene transformation.Nature communications · 2024Article
- Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides.Chemical science · 2024Article
- Bonding Situation of σ-E-H Complexes in Transition Metal and Main Group Compounds.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
Corrections and comments
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Authors and funding
4 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Copper and silver play important roles in acetylene transformations but isolable molecules with acetylene bonded to Cu(i) and Ag(i) ions are scarce. This report describes the stabilization of π-acetylene complexes of such metal ions supported by fluorinated and non-fluorinated, pyrazole-based chelators. These Cu(i) and Ag(i) complexes were formed readily in solutions under an atmosphere of excess acetylene and the appropriate ligand supported metal precursor, and could be isolated as crystalline solids, enabling complete characterization using multiple tools including X-ray crystallography. Molecules that display κ
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.