ArticleNature communications2022
3D and 2D aromatic units behave like oil and water in the case of benzocarborane derivatives.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
19 citing papers in PubMed.
- [60]Fullerene-Cluster Hybrids as Boron-Dense Delivery Nanoplatforms.Small science · 2026Article
- The concept of aromaticity after 200 years of benzene.Nature reviews. Chemistry · 2026Review
- Stereospecific alkenylation of carboranes: copper-catalyzed access to pyridylcarboranyl alkenes.Chemical science · 2026Article
- A Triple-Site GdACS applied materials & interfaces · 2025Article
- Reassessing the Possibility of π-σ-π Full Electron Delocalization Through 3D Aromatic Carboranes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Unveiling the True Identity of Carborane-Fused Phosphorus Heterocycles.Organic letters · 2025Article
- Post-coordination of Ru(ii) controlled regioselective B(4)-H acylmethylation ofChemical science · 2025Article
- Hydrogenated Planar Aluminum Clusters: A Density Functional Theory Study.Molecules (Basel, Switzerland) · 2025Article
- Carborane-Decorated Siloles with Highly Efficient Solid-State Emissions - What Drives the Photophysical Properties?Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Unraveling aromaticity: the dual worlds of pyrazole, pyrazoline, and 3D carborane.Beilstein journal of organic chemistry · 2025Article
- Carbon-Substituted Amines of the Cobalt Bis(dicarbollide) Ion: Stereochemistry and Acid-Base Properties.Inorganic chemistry · 2024Article
- A Pd-catalyzed route to carborane-fused boron heterocycles.Chemical science · 2024Article
- Optically induced charge-transfer in donor-acceptor-substituted p- and m- CNature communications · 2024Article
- Chemistry of Carbon-Substituted Derivatives of Cobalt Bis(dicarbollide)(1Molecules (Basel, Switzerland) · 2023Review
- Polyhedral Ferraboranes with Iron Carbonyl Vertices: Carbonyl Migration Processes in the Iron Tetracarbonyl Derivatives.The journal of physical chemistry. A · 2023Article
- Prototype for rapid test devices to detect residues of sulfonamides in chicken carcasses from traditional breeders in Surabaya, Indonesia.Veterinary world · 2023Article
- Adsorptive Separation of COACS applied materials & interfaces · 2023Article
- Synthesis, Characterization and DFT Study of a New Family of High-Energy Compounds Based onMolecules (Basel, Switzerland) · 2022Article
- Conjugation between 3D and 2D aromaticity: does it really exist? The case of carborane-fused heterocycles.Chemical science · 2022Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
A large number of 2D/2D and 3D/3D aromatic fusions that keep their aromaticity in the fused compounds have been synthesized. In addition, we have previously proven the electronic relationship between the 3D aromaticity of boron hydrides and the 2D aromaticity of PAHs. Here we report the possible existence of 3D/2D aromatic fusions that retain the whole aromaticity of the two units. Our conclusion is that such a 3D/2D aromatic combination is not possible due to the ineffective overlap between the π-MOs of the planar species and the n + 1 molecular orbitals in the aromatic cage that deter an effective electronic delocalization between the two fused units. We have also proven the necessary conditions for 3D/3D fusions to take place, and how aromaticity of each unit is decreased in 2D/2D and 3D/3D fusions.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.