Evidence map›Paper›PMID 35785464›Full record

ArticleChemphyschem : a European journal of chemical physics and physical chemistry2022

Photoinduced Intervalence Charge Transfers: Spectroscopic Tools to Study Fundamental Phenomena and Applications.

Ivana Ramírez-Wierzbicki, Agustina Cotic, Alejandro Cadranel

Abstract read
In one paragraph

Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Article
  3. Tuning Electron-Transfer Driving Force in Photosynthetic Special Pair Models.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Article
  4. Article
  5. The Excited-State Creutz-Taube Ion.Angewandte Chemie (International ed. in English) · 2022
    Article
  6. Photoinduced Intervalence Charge Transfers: Spectroscopic Tools to Study Fundamental Phenomena and Applications.Chemphyschem : a European journal of chemical physics and physical chemistry · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Ivana Ramírez-WierzbickiInstituto de Química Física de Materiales, Medio Ambiente y Energía (INQUIMAE), CONICET - Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina.ORCID 0000-0001-8227-7844
Agustina CoticInstituto de Química Física de Materiales, Medio Ambiente y Energía (INQUIMAE), CONICET - Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina.ORCID 0000-0003-0127-1147
Alejandro CadranelInstituto de Química Física de Materiales, Medio Ambiente y Energía (INQUIMAE), CONICET - Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina.ORCID 0000-0002-6597-4397

Funding

Agencia Nacional de Promoción Científica y Tecnológica 2018-00924Agencia Nacional de Promoción Científica y Tecnológica 2019-02410Consejo Nacional de Investigaciones Científicas y Técnicas PIP 11220200102757CO
6 · The paper itself

Abstract

The exploitation of excited state chemistry for solar energy conversion or photocatalysis has been continuously increasing, and the needs of a transition to a sustainable human development indicate this trend will continue. In this scenario, the study of mixed valence systems in the excited state offers a unique opportunity to explore excited state electron transfer reactivity, and, in a broader sense, excited state chemistry. This Concept article analyzes recent contributions in the field of photoinduced mixed valence systems, i. e. those where the mixed valence core is absent in the ground state but created upon light absorption. The focus is on the utilization of photoinduced intervalence charge transfer bands, detected via transient absorption spectroscopy, as key tools to study fundamental phenomena like donor/acceptor inversion, hole delocalization, coexistence of excited states and excited state nature, together with applications in molecular electronics.

Indexed as

Electron TransportHumansSpectrum Analysisdonor-acceptor interactionsexcited-state dynamicsphotoinduced intervalence charge transferphotoinduced mixed valencetransient absorption spectroscopy

Identifiers

PMID35785464
PMCPMC9805035

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.