Evidence map›Paper›PMID 35774857›Full record

ArticleFrontiers in chemistry2022

Relaxation Dynamics of Biomass-Derived Copolymers With Promising Gas-Barrier Properties.

Alejandro Sanz, Amelia Linares, Mari Cruz García-Gutiérrez, Aurora Nogales, Sandra Paszkiewicz, Agata Zubkiewicz, Anna Szymczyk, Tiberio A Ezquerra

Abstract read
In one paragraph

Article in Frontiers in chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed
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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Alejandro SanzInstituto de Estructura de La Materia, IEM-CSIC, Madrid, Spain.
Amelia LinaresInstituto de Estructura de La Materia, IEM-CSIC, Madrid, Spain.
Mari Cruz García-GutiérrezInstituto de Estructura de La Materia, IEM-CSIC, Madrid, Spain.
Aurora NogalesInstituto de Estructura de La Materia, IEM-CSIC, Madrid, Spain.
Sandra PaszkiewiczDepartment of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology, Szczecin, Poland.
Agata ZubkiewiczDepartment of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology, Szczecin, Poland.
Anna SzymczykDepartment of Mechanical Engineering and Mechatronics, West Pomeranian University of Technology, Szczecin, Poland.
Tiberio A EzquerraInstituto de Estructura de La Materia, IEM-CSIC, Madrid, Spain.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

This article presents an experimental study on the relaxation dynamics of a series of random copolymers based on bio-friendly comonomers with interesting gas barrier properties. We analyze the relaxation response in the glassy and ultraviscous regime of poly (trimethylene furanoate/sebacate) random copolymers via dielectric spectroscopy. We report lower values of dynamic fragility [a dimensionless index introduced in 1985 (Angell, Relaxations in Complex Systems, 1985)] in comparison to popular polyesters widely used in industry, such as poly (ethylene terephthalate), suggesting that the amorphous phase of these furanoate-based polyesters adopt an efficient chain packing. This is consistent with their low permeability to gases. We also discuss on different equations (phenomenological and theory-based approaches) for fitting the temperature-evolution of the alpha relaxation time.

Indexed as

dielectric spectroscopydynamicsglass transitionpolyfuranoatesrandom copolymers

Identifiers

PMID35774857
PMCPMC9237226

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.