ArticleChemical science2022
Water as a monomer: synthesis of an aliphatic polyethersulfone from divinyl sulfone and water.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Functional Polymeric Membrane Materials: A Perspective from Versatile Methods and Modification to Potential Applications.Polymer science & technology (Washington, D.C.) · 2025Review
- A Greener and More Scalable Synthesis of Biogenic Polydisulfides from Lipoic Acid.ChemSusChem · 2025Article
- Thermally and Base-Triggered "Debond-on-Demand" Chain-Extended Polyurethane Adhesives.Macromolecules · 2025Article
- Water as a Reactant: DABCO-Catalyzed Hydration of Activated Alkynes for the Synthesis of Divinyl Ethers.The Journal of organic chemistry · 2024Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Using water as a monomer in polymerization reactions presents a unique and exquisite strategy towards more sustainable chemistry. Herein, the feasibility thereof is demonstrated by the introduction of the oxa-Michael polyaddition of water and divinyl sulfone. Upon nucleophilic or base catalysis, the corresponding aliphatic polyethersulfone is obtained in an interfacial polymerization at room temperature in high yield (>97%) within an hour. The polyethersulfone is characterized by relatively high molar mass averages and a dispersity around 2.5. The polymer was tested as a solid polymer electrolyte with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) as the salt. Free-standing amorphous membranes were prepared by a melt process in a solvent-free manner. The polymer electrolyte containing 15 wt% LiTFSI featured an oxidative stability of up to 5.5 V
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Registered trials
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