ArticleChemical science2022
Enantioselective assembly and recognition of heterochiral porous organic cages deduced from binary chiral components.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Confined Chiral Microenvironments in Discrete Supramolecular Assemblies.Chem & bio engineering · 2026Review
- A self-assembled macrocycle with a non-closed structure for hierarchically upgraded self-assembly.Chemical science · 2026Article
- Chiral covalent organic cages: Construction and chiral functions.Smart molecules : open access · 2025Review
- Regioselective Substitution of BINOL.Chemical reviews · 2024Review
- Preferential molecular recognition of heterochiral guests within a cyclophane receptor.Nature communications · 2023Article
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Chiral recognition and discrimination is not only of significance in biological processes but also a powerful method to fabricate functional supramolecular materials. Herein, a pair of heterochiral porous organic cages (HPOC-1), out of four possible enantiomeric products, with mirror stereoisomeric crystal structures were cleanly prepared by condensation occurring in the exclusive combination of cyclohexanediamine and binaphthol-based tetraaldehyde enantiomers. Nuclear magnetic resonance and luminescence spectroscopy have been employed to monitor the assembly process of HPOC-1, revealing the clean formation of heterochiral organic cages due to the enantioselective recognition of (
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