ArticleNature communications2022
Promoting biomass electrooxidation via modulating proton and oxygen anion deintercalation in hydroxide.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 39 papers.
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Who cites it
39 citing papers in PubMed, 266 citations in OpenAlex.
- Mesoporous Anti-Perovskite CuNiAngewandte Chemie (International ed. in English) · 2026Article
- Asymmetric Ru─O sites in self-activated catalysts for efficient electrochemical methanol oxidation and industrial-scale hydrogen generation.Science advances · 2026Article
- Regulating adsorption selectivity by charge-polarized AuNature communications · 2026Article
- Mechanistic Study of Glycerol Electro-Oxidation on Ni(OH)Journal of the American Chemical Society · 2026Article
- Built-in electric field engineering in CoNature communications · 2026Article
- Revealing How Acid Sites Enhance the Electrocatalytic Glycerol Oxidation Performance on Pt Loaded Zeolite-Carbon Composite Materials.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Oxyanions stabilized low-coordinated nickel species for efficient and durable nucleophilic electrooxidation.Nature communications · 2025Article
- Efficient glyceric acid electrosynthesis from waste glycerol on rare-earth-metal-alloyed mesoporous PtPb nanosheets.National science review · 2025Article
- Saturated Alcohols Electrocatalytic Oxidations on Ni-Co Bimetal Oxide Featuring Balanced B- and L-Acidic Active Sites.Nano-micro letters · 2025Article
- Pd@PdBOScience advances · 2025Article
- 2D Conjugated Metal-Organic Frameworks as Electrocatalysts for Boosting Glycerol Upgrading Coupled with Hydrogen Production.Angewandte Chemie (International ed. in English) · 2025Article
- Coupling of CuO@NiBiOAngewandte Chemie (International ed. in English) · 2025Article
- Stable Ni(II) sites in Prussian blue analogue for selective, ampere-level ethylene glycol electrooxidation.Nature communications · 2025Article
- Mechanistic Insights into Glycerol Oxidation to High-Value Chemicals via Metal-Based Catalysts.Molecules (Basel, Switzerland) · 2025Review
- A Copper-Zinc Cyanamide Solid-Solution Catalyst with Tailored Surface Electrostatic Potentials Promotes Asymmetric N-Intermediate Adsorption in Nitrite Electroreduction.Journal of the American Chemical Society · 2025Article
- In Situ Modulation of NiFeOOH Coordination Environment for Enhanced Electrocatalytic-Conversion of Glucose and Energy-Efficient Hydrogen Production.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Identifying Reactive Trends in Glycerol Electro-Oxidation Using an Automated Screening Approach: 28 Ways to Electrodeposit an Au Electrocatalyst.ACS catalysis · 2025Article
- Time-resolved spectroscopy uncovers deprotonation-induced reconstruction in oxygen-evolution NiFe-based (oxy)hydroxides.Nature communications · 2025Article
- Tackling activity-stability paradox of reconstructed NiIrONature communications · 2024Article
- Sulfur filling activates vacancy-induced C-C bond cleavage in polyol electrooxidation.National science review · 2024Article
Corrections and comments
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Authors and funding
8 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The redox center of transition metal oxides and hydroxides is generally considered to be the metal site. Interestingly, proton and oxygen in the lattice recently are found to be actively involved in the catalytic reactions, and critically determine the reactivity. Herein, taking glycerol electrooxidation reaction as the model reaction, we reveal systematically the impact of proton and oxygen anion (de)intercalation processes on the elementary steps. Combining density functional theory calculations and advanced spectroscopy techniques, we find that doping Co into Ni-hydroxide promotes the deintercalation of proton and oxygen anion from the catalyst surface. The oxygen vacancies formed in NiCo hydroxide during glycerol electrooxidation reaction increase d-band filling on Co sites, facilitating the charge transfer from catalyst surface to cleaved molecules during the 2
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.