ArticleThe journal of physical chemistry letters2022
Identifying Vibrations that Control Non-adiabatic Relaxation of Polaritons in Strongly Coupled Molecule-Cavity Systems.
Article in The journal of physical chemistry letters, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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15 citing papers in PubMed.
- Cavity-modified exciton-exciton annihilation in disordered molecular systems.Physical chemistry chemical physics : PCCP · 2026Article
- Quantifying the Number of Dark, Gray, and Bright States as a Function of the Spectral Overlap in Polaritonic Systems.Nano letters · 2026Article
- Direct Readout of Excited-State Lifetimes in Chlorin Chromophores under Electronic Strong Coupling.Journal of the American Chemical Society · 2026Article
- Perspective on Many-Body Methods for Molecular Polaritonic Systems.Journal of chemical theory and computation · 2025Review
- Disentangling Enhanced Diffusion and Ballistic Motion of Excitons Coupled to Bloch Surface Waves with Molecular Dynamics Simulations.The journal of physical chemistry letters · 2025Article
- Quantum dynamics simulation of exciton-polariton transport.Nature communications · 2025Article
- Radiative pumping vs vibrational relaxation of molecular polaritons: a bosonic mapping approach.Nature communications · 2025Article
- Role of Vibronic Coupling for the Dynamics of Intersystem Crossing in EuJournal of chemical theory and computation · 2025Article
- Thermal disorder prevents the suppression of ultra-fast photochemistry in the strong light-matter coupling regime.Nature communications · 2024Article
- Photochemical initiation of polariton-mediated exciton propagation.Nanophotonics (Berlin, Germany) · 2024Article
- Tuning the Coherent Propagation of Organic Exciton-Polaritons through the Cavity Q-factor.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Multi-scale molecular dynamics simulations of enhanced energy transfer in organic molecules under strong coupling.Nature communications · 2023Article
- Theoretical Advances in Polariton Chemistry and Molecular Cavity Quantum Electrodynamics.Chemical reviews · 2023Review
- The role of dephasing for dark state coupling in a molecular Tavis-Cummings model.The Journal of chemical physics · 2023Article
- Ab Initio Molecular Cavity Quantum Electrodynamics Simulations Using Machine Learning Models.Journal of chemical theory and computation · 2023Article
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Authors and funding
5 authors.
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Abstract
The strong light-matter coupling regime, in which excitations of materials hybridize with excitations of confined light modes into polaritons, holds great promise in various areas of science and technology. A key aspect for all applications of polaritonic chemistry is the relaxation into the lower polaritonic states. Polariton relaxation is speculated to involve two separate processes: vibrationally assisted scattering (VAS) and radiative pumping (RP), but the driving forces underlying these two mechanisms are not fully understood. To provide mechanistic insights, we performed multiscale molecular dynamics simulations of tetracene molecules strongly coupled to the confined light modes of an optical cavity. The results suggest that both mechanisms are driven by the same molecular vibrations that induce relaxation through nonadiabatic coupling between dark states and polaritonic states. Identifying these vibrational modes provides a rationale for enhanced relaxation into the lower polariton when the cavity detuning is resonant with specific vibrational transitions.
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