Evidence map›Paper›PMID 35770382›Full record

ArticleJournal of the American Chemical Society2022

Direct Stereodivergent Olefination of Carbonyl Compounds with Sulfur Ylides.

Jérémy Merad, Phillip S Grant, Tobias Stopka, Juliette Sabbatani, Ricardo Meyrelles, Alexander Preinfalk, Ján Matyasovsky, Boris Maryasin, Leticia González, Nuno Maulide

Open access · hybridAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
3.9field-weighted citation impact, top 5% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 37 citations in OpenAlex.

  1. Article
  2. Review
  3. Stereoselective Copper-Catalyzed Olefination of Imines.Angewandte Chemie (International ed. in English) · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 1 institution in 1 country.

Jérémy MeradInstitute of Organic Chemistry, University of Vienna, 1090 Vienna, Austria.
Phillip S GrantInstitute of Organic Chemistry, University of Vienna, 1090 Vienna, Austria.ORCID 0000-0001-7077-8756
Tobias StopkaInstitute of Organic Chemistry, University of Vienna, 1090 Vienna, Austria.
Juliette SabbataniInstitute of Organic Chemistry, University of Vienna, 1090 Vienna, Austria.
Ricardo MeyrellesInstitute of Organic Chemistry, University of Vienna, 1090 Vienna, Austria.
Alexander PreinfalkInstitute of Organic Chemistry, University of Vienna, 1090 Vienna, Austria.
Ján MatyasovskyInstitute of Organic Chemistry, University of Vienna, 1090 Vienna, Austria.
Boris MaryasinInstitute of Organic Chemistry, University of Vienna, 1090 Vienna, Austria.ORCID 0000-0001-7943-7333
Leticia GonzálezInstitute of Theoretical Chemistry, University of Vienna, 1090 Vienna, Austria.ORCID 0000-0001-5112-794X
Nuno MaulideInstitute of Organic Chemistry, University of Vienna, 1090 Vienna, Austria.ORCID 0000-0003-3643-0718
University of Vienna · AT

Funding

Austrian Science Fund FWF M 2997
6 · The paper itself

Abstract

The reactivity of phosphorus and sulfur ylides toward carbonyl compounds constitutes a well-known dichotomy that is a common educational device in organic chemistry─the former gives olefins, while the latter gives epoxides. Herein, we report a stereodivergent carbonyl olefination that challenges this dichotomy, showcasing thiouronium ylides as valuable olefination reagents. With this method, aldehydes are converted to

Indexed as

AldehydesAlkenesIndicators and ReagentsMolecular StructureSulfurAldehydesAlkenesIndicators and ReagentsSulfur

Identifiers

PMID35770382
PMCPMC9284548
OpenAlexW4283747700

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.