ArticleNature communications2022
Perfluorocycloparaphenylenes.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
15 citing papers in PubMed, 42 citations in OpenAlex.
- Cross-dehydrogenative coupling macrocyclization for the construction of donor-acceptor nanohoops.Chemical science · 2026Article
- Bridging [8]cyclo-Chemical science · 2026Article
- Cycloazulenylene.Angewandte Chemie (International ed. in English) · 2026Article
- Cyclo-Journal of the American Chemical Society · 2026Article
- A Precisely Bromo-Functionalized [9]Cycloparaphenylene as a Platform for Late-Stage Multisite π-Extension Toward Chiral Nanohoops.Angewandte Chemie (International ed. in English) · 2026Article
- Macrocyclic geminal diols: synthesis, structures, stability and photophysical properties.Chemical science · 2026Article
- Precision Molecular Engineering of Alternating Donor-Acceptor Cycloparaphenylenes: Multidimensional Optoelectronic Response and Chirality Modulation via Polarization-Driven Charge Transfer.Molecules (Basel, Switzerland) · 2025Article
- Cycloparaazine, a full-azine carbon nanoring.Nature communications · 2025Article
- Polarization-Induced Quantum Confinement of Negative Charge Carriers by Organic Nanoporous Frameworks.Angewandte Chemie (International ed. in English) · 2025Article
- Thiophene-fused aromatic belts.Nature communications · 2025Article
- Easy access to polyhalogenated biaryls: regioselective (di)halogenation of hypervalent bromines and chlorines.Chemical science · 2024Article
- Photoinduced Electron Transfer in Inclusion Complexes of Carbon Nanohoops.Accounts of chemical research · 2024Article
- A dodecamethoxy[6]cycloparaphenylene consisting entirely of hydroquinone ethers: unveiling in-plane aromaticity through a rotaxane structure.Nature communications · 2023Article
- Synthesis and metalation of polycatechol nanohoops derived from fluorocycloparaphenylenes.Chemical science · 2023Article
- Theoretical exploration of noncovalent interactions in ScRSC advances · 2023Article
Corrections and comments
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Authors and funding
10 authors at 5 institutions in 1 country.
Funding
Abstract
Perfluorinated aromatic compounds, the so-called perfluoroarenes, are widely used in materials science owing to their high electron affinity and characteristic intermolecular interactions. However, methods to synthesize highly strained perfluoroarenes are limited, which greatly limits their structural diversity. Herein, we report the synthesis and isolation of perfluorocycloparaphenylenes (PFCPPs) as a class of ring-shaped perfluoroarenes. Using macrocyclic nickel complexes, we succeeded in synthesizing PF[n]CPPs (n = 10, 12, 14, 16) in one-pot without noble metals. The molecular structures of PF[n]CPPs (n = 10, 12, 14) were determined by X-ray crystallography to confirm their tubular alignment. Photophysical and electrochemical measurements revealed that PF[n]CPPs (n = 10, 12, 14) exhibited wide HOMO-LUMO gaps, high reduction potentials, and strong phosphorescence at low temperature. PFCPPs are not only useful as electron-accepting organic materials but can also be used for accelerating the creation of topologically unique molecular nanocarbon materials.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.