ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Transformations of Strained Three-Membered Rings a Common, Yet Overlooked, Motif in Heavy-Atom Tunneling Reactions.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
4 citing papers in PubMed, 20 citations in OpenAlex.
- The Different Levels of Quantum: A Methodological-Philosophical Portrait of Computational Quantum Chemistry.ACS physical chemistry Au · 2026Review
- Experimental observation of quantum mechanical fluorine tunnelling.Nature communications · 2025Article
- Norcaradiene-Cycloheptatriene Equilibrium: A Heavy-Atom Quantum Tunneling Case.The Journal of organic chemistry · 2024Article
- Transformations of Strained Three-Membered Rings a Common, Yet Overlooked, Motif in Heavy-Atom Tunneling Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
Corrections and comments
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Authors and funding
1 author at 1 institution in 2 countries.
Funding
Abstract
Quantum mechanical tunneling has long been recognized as an important phenomenon when considering transformations dominated by a lightweight hydrogen atom. Tunneling of heavier atoms like carbon, initially dismissed as negligible, has seen a quickly increasing number of computationally predicted and/or experimentally confirmed examples over the last decade, thus highlighting its importance for a wide variety of reactions. However, no common structural motif has been pointed out within these seemingly unconnected examples, strongly limiting the predictability of the impact of heavy-atom tunneling on a given reaction. This Concept article will provide this perspective and showcase how the recognition of the formation and cleavage of three-membered rings as common motif can inform the prediction of and research into heavy-atom tunneling reactions.
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Registered trials
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