Evidence map›Paper›PMID 35762510›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022

Spectroscopic Signature of Dynamical Instability of the Aqueous Complex in the Brown-Ring Nitrate Test.

Ambar Banerjee, Michael R Coates, Michael Odelius

Abstract read
PubMed Publisher
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Ambar BanerjeeDepartment of Physics, Stockholm University, Albanova University Center, SE-106 91, Stockholm, Sweden.ORCID http://orcid.org/0000-0001-6113-7033
Michael R CoatesDepartment of Physics, Stockholm University, Albanova University Center, SE-106 91, Stockholm, Sweden.ORCID http://orcid.org/0000-0001-6908-5434
Michael OdeliusDepartment of Physics, Stockholm University, Albanova University Center, SE-106 91, Stockholm, Sweden.ORCID http://orcid.org/0000-0002-7023-2486

Funding

Carl Tryggers Stiftelse för Vetenskaplig Forskning CTS18:285H2020 Marie Skłodowska-Curie Actions 860553Vetenskapsrådet 2018-05973Vetenskapsrådet 2021-04521
6 · The paper itself

Abstract

The chemistry of the brown-ring test has been investigated for nearly a century. Though recent studies have focused on solid state structure determination and measurement of spectra, mechanistic details and kinetics, the aspects of solution structure and dynamics remain unknown. We have studied structural fluctuations of the brown-ring complex in aqueous solution with ab-initio molecular dynamics simulations, from which we identified that the classically established pseudo-octahedral [Fe(H

Indexed as

ab initio calculationsiron nitrosyl complexmolecular dynamicsmulti-reference wave-functionUV-vis spectra

Identifiers

PMID35762510

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.