ArticleNature communications2022
A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran.
Article in Nature communications, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Orbital Symmetry Matching in Tailored Bimetal Oxides: Steering 5-Hydroxymethylfurfural Electrooxidation via Concurrent Activation of spSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Edge Sulfur Vacancies on MoSAngewandte Chemie (International ed. in English) · 2026Article
- Amide-engineered copper nitride for shortcut-pathway-locked electroreduction of concentrated hydroxymethylfurfural.Nature communications · 2026Article
- Integrating integrated circuit wastewater into the metal catalyst supply chain.Nature communications · 2026Article
- Cobalt single-atom and nano catalysts for efficient transfer hydrodeoxygenation of vanillin with formic acid.Communications chemistry · 2026Article
- Stepwise hydrogen spillover-engineered synergistic sites enable near-quantitative conversion of waste PET to p-xylene.Nature communications · 2026Article
- Creating hydrophobic nanopockets in metal-organic frameworks to promote hydrodeoxygenation of lignin derivatives under ambient conditions.Chemical science · 2025Article
- Cascade Electric Field in ZnInSmall (Weinheim an der Bergstrasse, Germany) · 2025Article
- Homolytic HNature communications · 2024Article
- Enhancing polyol/sugar cascade oxidation to formic acid with defect rich MnONature communications · 2023Article
- Neutron Scattering Studies of Heterogeneous Catalysis.Chemical reviews · 2023Review
- CoO-Co Heterojunction Covered with Carbon Enables Highly Efficient Integration of Hydrogen Evolution and 5-Hydroxymethylfurfural Oxidation.Molecules (Basel, Switzerland) · 2023Article
- Tripodal Pd metallenes mediated by NbNature communications · 2023Article
- Controlled Oxidation of Cobalt Nanoparticles to Obtain Co/CoO/CoNanomaterials (Basel, Switzerland) · 2022Article
- Tailoring the catalytic performance of Cu/SiOFrontiers in chemistry · 2022Article
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Authors and funding
14 authors.
Funding
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Abstract
The development of precious-metal-free catalysts to promote the sustainable production of fuels and chemicals from biomass remains an important and challenging target. Here, we report the efficient hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran over a unique core-shell structured catalyst, Co@CoO that affords the highest productivity among all catalysts, including noble-metal-based catalysts, reported to date. Surprisingly, we find that the catalytically active sites reside on the shell of CoO with oxygen vacancies rather than the metallic Co. The combination of various spectroscopic experiments and computational modelling reveals that the CoO shell incorporating oxygen vacancies not only drives the heterolytic cleavage, but also the homolytic cleavage of H
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