ArticleAngewandte Chemie (International ed. in English)2022
An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 32 citations in OpenAlex.
- Photoinduced reduction of nitro(hetero)arenes with earth-abundant FeClRSC advances · 2026Article
- Monosubstituted N-Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Review
- The recent progress in the catalytic conversion of nitroarene into amino arene catalyzed by heterogeneous metal based nano catalyst.Frontiers in chemistry · 2026Review
- Adaptive Rhodium Catalysis with a Lewis‑Acidic Secondary Sphere for Divergent Hydrogenation of Propargylic Alcohols.Angewandte Chemie (International ed. in English) · 2025Article
- Borane-functionalized heteroscorpionate copper complexes as catalysts for azide-alkyne cycloaddition.Dalton transactions (Cambridge, England : 2003) · 2025Article
- Design and Understanding of Adaptive Hydrogenation Catalysts Triggered by the HJournal of the American Chemical Society · 2024Article
- Zinc-Catalyzed Hydroboration of Carbon Dioxide Amplified by Borane-Tethered Heteroscorpionate Bis(Pyrazolyl)methane Ligands.Inorganic chemistry · 2024Article
- Diazines and Triazines as Building Blocks in Ligands for Metal-Mediated Catalytic Transformations.ACS organic & inorganic Au · 2024Review
- A Cooperative Cobalt-Driven System for One-Carbon Extension in the Synthesis of (Journal of the American Chemical Society · 2023Article
- Ligand Postsynthetic Functionalization with Fluorinated Boranes and Implications in Hydrogenation Catalysis.ACS catalysis · 2023Article
- An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
9 authors at 2 institutions in 1 country.
Funding
Abstract
An adaptive catalytic system that provides control over the nitroarene hydrogenation network to prepare a wide range of aniline and hydroxylamine derivatives is presented. This system takes advantage of a delicate interplay between a rhodium(III) center and a Lewis acidic borane introduced in the secondary coordination sphere of the metal. The high chemoselectivity of the catalyst in the presence of various potentially vulnerable functional groups and its readiness to be deployed at a preparative scale illustrate its practicality. Mechanistic studies and density functional theory (DFT) methods were used to shed light on the mode of functioning of the catalyst and elucidate the origin of adaptivity. The competition for interaction with boron between a solvent molecule and a substrate was found crucial for adaptivity. When operating in THF, the reduction network stops at the hydroxylamine platform, whereas the reaction can be directed to the aniline platform in toluene.
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