ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
Peri-Decoration of a Tetraazaperylene with Urea Units: Chiral Octaazaperopyrenedioxides (OAPPDOs) and Their Optical and Chiroptical Properties.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
4 citing papers in PubMed, 15 citations in OpenAlex.
- Dynamics and Conformational Stability of Chiral Bay-Phenolate-Substituted Twisted Octaazaperopyrenedioxides (OAPPDOs).Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Synthesis of Aza-indeno-aza-fluoranthene and Constitutional Isomers by Ring-Size Selective C-H Activation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Peri-Functionalized Tetraazaperylenes: Strong Emitters for Molecular Polaritonics.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Peri-Decoration of a Tetraazaperylene with Urea Units: Chiral Octaazaperopyrenedioxides (OAPPDOs) and Their Optical and Chiroptical Properties.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
Octaazaperopyrenedioxides (OAPPDOs) are a new class of fluorescent polycyclic aromatic hydrocarbons based on a tetraazaperylene core that is formally condensed with N-substituted urea units in the two opposite peri positions. Here, we report the synthesis of series of substituted OAPPDO derivatives with different N-substitution patterns (H, alkyl, benzyl) in the peri positions, including bay-chlorinated OAPPDOs. Starting from the latter, a series of bay-arylated OAPPDOs was synthesized by Suzuki cross coupling, which resulted in the formation of helically chiral OAPPDO derivatives. The electrochemical and photophysical properties were investigated by UV/Vis and fluorescence spectroscopy as well as cyclic voltammetry. The P and M enantiomers of a phenylated OAPPDO were separated by semipreparative HPLC and further analyzed by CD spectroscopy. The frontier orbital energies, the mechanism of the isomerization, the electronic excitation and the CD spectrum (TD-DFT) were computed and compared to the experimental data. The reversible 1e
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.