Evidence map›Paper›PMID 35756513›Full record

ArticleChemical science2022

Orbital analysis of bonding in diarylhalonium salts and relevance to periodic trends in structure and reactivity.

Shubhendu S Karandikar, Avik Bhattacharjee, Bryan E Metze, Nicole Javaly, Edward J Valente, Theresa M McCormick, David R Stuart

Abstract read
In one paragraph

Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Review
  2. Review
  3. Article
  4. Article
  5. Cyclic Homo- and Heterohalogen Di-λJournal of the American Chemical Society · 2023
    Article
  6. Recent progress in alkynylation with hypervalent iodine reagents.Chemical communications (Cambridge, England) · 2023
    Review
  7. Cyclic Diaryl λJournal of the American Chemical Society · 2023
    Article
  8. A Quantum-chemical Analysis on the Lewis Acidity of Diarylhalonium Ions.Chemphyschem : a European journal of chemical physics and physical chemistry · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Shubhendu S KarandikarDepartment of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.
Avik BhattacharjeeDepartment of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.
Bryan E MetzeDepartment of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.
Nicole JavalyDepartment of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.ORCID https://orcid.org/0000-0001-5504-5431
Edward J ValenteDepartment of Chemistry, University of Portland Portland OR 97203 USA.
Theresa M McCormickDepartment of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.
David R StuartDepartment of Chemistry, Portland State University Portland OR 97201 USA dstuart@pdx.edu.ORCID https://orcid.org/0000-0003-3519-9067

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Diarylhalonium compounds provide new opportunities as reagents and catalysts in the field of organic synthesis. The three center, four electron (3c-4e) bond is a center piece of their reactivity, but structural variation among the diarylhaloniums, and in comparison with other λ

Identifiers

PMID35756513
PMCPMC9172531

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.