ArticleChemical science2022
Accessing the triplet state of perylenediimide by radical-enhanced intersystem crossing.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- A Qualitative Approach for Predicting Enhanced Intersystem Crossing in Chromophore-Radical Systems.The journal of physical chemistry letters · 2026Article
- Conformational switching modulates excited-state pathways in a cofacial perylene dimer.Chemical science · 2026Article
- Coherent Control over Nuclear Hyperpolarization Using an Optically Initializable Chromophore-Radical System.Journal of the American Chemical Society · 2025Article
- Oxygen-Mediated Sequential Down-Conversion in Perylenediimides.Artificial photosynthesis (Washington, D.C.) · 2025Article
- Supramolecular dyads as photogenerated qubit candidates.Nature chemistry · 2025Article
- Room-Temperature Optical Spin Polarization of an Electron Spin Qudit in a Vanadyl-Free Base Porphyrin Dimer.Journal of the American Chemical Society · 2025Article
- Influence of the substitution position on spin communication in photoexcited perylene-nitroxide dyads.Chemical science · 2024Article
- Radical Spin Polarization and Magnetosensitivity from Reversible Energy Transfer.The journal of physical chemistry letters · 2024Article
- PDI-trityl dyads as photogenerated molecular spin qubit candidates.Chemical science · 2023Article
- Formylation as a Chemical Tool to Modulate the Performance of Photosensitizers Based on Boron Dipyrromethene Dimers.International journal of molecular sciences · 2023Article
- Distance dependence of enhanced intersystem crossing in BODIPY-nitroxide dyads.Chemical science · 2023Article
- Panchromatic Light-Absorbing [70]Fullerene-Perylene-BODIPY Triad with Cascade of Energy Transfer as an Efficient Singlet Oxygen Sensitizer.Molecules (Basel, Switzerland) · 2023Article
- Minimal Active Space: NOSCF and NOSI in Multistate Density Functional Theory.Journal of chemical theory and computation · 2022Review
- Calculation of exchange couplings in the electronically excited state of molecular three-spin systems.Chemical science · 2022Article
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Authors and funding
9 authors.
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No grant is acknowledged in the PubMed record.
Abstract
Owing to their exceptional photophysical properties and high photostability, perylene diimide (PDI) chromophores have found various applications as building blocks of materials for organic electronics. In many light-induced processes in PDI derivatives, chromophore excited states with high spin multiplicities, such as triplet or quintet states, have been revealed as key intermediates. The exploration of their properties and formation conditions is thus expected to provide invaluable insight into their underlying photophysics and promises to reveal strategies for increasing the performance of optoelectronic devices. However, accessing these high-multiplicity excited states of PDI to increase our mechanistic understanding remains a difficult task, due to the fact that the lowest excited singlet state of PDI decays with near-unity quantum yield to its ground state. Here we make use of radical-enhanced intersystem crossing (EISC) to generate the PDI triplet state in high yield. One or two 2,2,6,6-tetramethylpiperidinyloxyl (TEMPO) stable radicals were covalently attached to the imide position of PDI chromophores with and without
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