ArticleJournal of the American Chemical Society2022
Ketone-Olefin Coupling of Aliphatic and Aromatic Carbonyls Catalyzed by Excited-State Acridine Radicals.
Article in Journal of the American Chemical Society, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
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Who cites it
25 citing papers in PubMed.
- Article
- Intermolecular Reductive Coupling of Ketones and Alkenes under Ferrioxalate Photocatalysis.Journal of the American Chemical Society · 2026Article
- Redox-neutral ketone-olefin coupling enabled by mild ketone-to-ketyl-type radical conversion.Nature chemistry · 2026Article
- Aldehyde-Olefin Couplings by Photoinduced Reduction of Electron-Deficient Olefins with Hantzsch Ester Anions.Angewandte Chemie (International ed. in English) · 2026Article
- Article
- Virtual Ligand-Assisted Screening for the Generation of Ketyl Radicals from Alkyl Ketones via Photoexcited Palladium Catalysis.Journal of the American Chemical Society · 2025Article
- Article
- Counterintuitive Photochemistry of an Isolated Acridinyl Radical: ConPET via Preassembly, Solvated Electrons or a Long-Lived Excited State?Angewandte Chemie (International ed. in English) · 2025Article
- Photochemically Enabled Total Syntheses of Stemoamide Alkaloids.Journal of the American Chemical Society · 2025Article
- Excited Organic Radicals in Photoredox Catalysis.JACS Au · 2025Review
- Metallaphotoredox-catalyzed alkynylcarboxylation of alkenes with CONature communications · 2025Article
- Catalytic Aldehyde-Alkyne Couplings Triggered by Ketyl Radicals.Organic letters · 2024Article
- Aldehyde-Olefin Couplings Via Sulfoxylate-Mediated Oxidative Generation of Ketyl Radical Anions.Journal of the American Chemical Society · 2024Article
- Harnessing the potential of acyl triazoles in bifunctional cobalt-catalyzed radical cross-coupling reactions.Nature communications · 2024Article
- Mild Photochemical Reduction of Alkenes and Heterocycles via Thiol-Mediated Formate Activation.Organic letters · 2024Article
- Alkyl Cyclopropyl Ketones in Catalytic Formal [3 + 2] Cycloadditions: The Role of SmIJournal of the American Chemical Society · 2024Article
- Reductive Cross-Coupling of Olefins via a Radical Pathway.Journal of the American Chemical Society · 2023Article
- Photo-Induced, Phenylhydrazine-Promoted Transition-Metal-Free Dehalogenation of Aryl Fluorides, Chlorides, Bromides, and Iodides.Molecules (Basel, Switzerland) · 2023Article
- Ketyl Radical Coupling Enabled by Polycyclic Aromatic Hydrocarbon Electrophotocatalysts.Journal of the American Chemical Society · 2023Article
- Reductive photoredox transformations of carbonyl derivatives enabled by strongly reducing photosensitizers.Chemical science · 2023Article
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4 authors.
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Abstract
Ketone-olefin coupling reactions are common methods for the formation of carbon-carbon bonds. This reaction class typically requires stoichiometric or super stoichiometric quantities of metal reductants, and catalytic variations are limited in application. Photoredox catalysis has offered an alternative method toward ketone-olefin coupling reactions, although most methods are limited in scope to easily reducible aromatic carbonyl compounds. Herein, we describe a mild, metal-free ketone-olefin coupling reaction using an excited-state acridine radical super reductant as a photoredox catalyst. We demonstrate both intramolecular and intermolecular ketone-olefin couplings of aliphatic and aromatic ketones and aldehydes. Mechanistic evidence is also presented supporting an "
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