ArticleChemical science2022
Insights into electrochemiluminescence dynamics by synchronizing real-time electrical, luminescence, and mass spectrometric measurements.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
7 citing papers in PubMed, 33 citations in OpenAlex.
- Mechanistic insights into electrochemiluminescence: fueling advances in bioanalysis and imaging.Chemical science · 2026Review
- Sensitive chemiluminescent determination of CYFRA 21-1 as a lung cancer marker using PVP/NiO-supported luminol@ZIF-67-aptamer composite.Mikrochimica acta · 2025Article
- Screening and dissecting electroorganic synthesis by mass spectrometry decoupling of electrode and homogeneous processes.Nature communications · 2025Article
- Ratiometric electrochemiluminescence sensing and intracellular imaging of ClOAnalytical and bioanalytical chemistry · 2024Article
- Fragile intermediate identification and reactivity elucidation in electrochemical oxidative α-C(spChemical science · 2023Article
- Reversibly Tuning Electrochemiluminescence with Stimulated Emission Route for Single-Cell Imaging.Research (Washington, D.C.) · 2023Article
- A temperature-tuned electrochemiluminescence layer for reversibly imaging cell topography.Chemical science · 2022Article
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Electrochemiluminescence (ECL) comprises a sophisticated cascade of reactions. Despite advances in mechanistic studies by electrochemistry and spectroscopy, a lack of access to dynamic molecular information renders many plausible ECL pathways unclear or unproven. Here we describe the construction of a real-time ECL mass spectrometry (MS) platform (RT-Triplex) for synchronization of dynamic electrical, luminescent, and mass spectrometric outputs during ECL events. This platform allows immediate and continuous sampling of newly born species at the Pt wire electrode of a capillary electrochemical (EC) microreactor into MS, enabling characterization of short-lived intermediates and the multi-step EC processes. Two ECL pathways of luminol are validated by observing the key intermediates α-hydroxy hydroperoxide and diazaquinone and unraveling their correlation with applied voltage and ECL emission. Moreover, a "catalytic ECL route" of boron dipyrromethene (BODIPY) involving homogeneous oxidation of tri-
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.