ReviewACS nanoscience Au2022
Lanthanides Singing the Blues: Their Fascinating Role in the Assembly of Gigantic Molybdenum Blue Wheels.
Review in ACS nanoscience Au, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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Who cites it
9 citing papers in PubMed.
- Cation-Directed Host-Guest Assembly and Reversible Wheel to Cluster Interconversion in a 20-Molybdate System.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Spontaneous assemblies of gigantic polyoxomolybdates; from structure and properties to synthetic methods.Dalton transactions (Cambridge, England : 2003) · 2026Review
- Organophosphonate Ligation Approach for the Controlled Assembly of Gigantic Polyoxometalate Clusters.Journal of the American Chemical Society · 2026Article
- Polyoxometalates in environmental remediation and energy storage.Environmental science. Nano · 2026Review
- Speciation atlas of polyoxometalates in aqueous solution (Part II): Molybdenum browns.Science advances · 2025Article
- Compression of Molybdenum Blue Polyoxometalate Cluster Rings.Journal of the American Chemical Society · 2025Article
- Trisubstituted 4f- and 4d tungstoantimonates as artificial phosphoesterases for nerve agent degradation.Chemical communications (Cambridge, England) · 2022Article
- Comment on molybdenum polyoxo clusters: from the `Blues' to the `Reds'.Acta crystallographica. Section C, Structural chemistry · 2022Article
- Synthesis and characterization of the `Japanese rice-ball'-shaped Molybdenum Blue NaActa crystallographica. Section C, Structural chemistry · 2022Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Molybdenum blues (MBs) are a distinct class of polyoxometalates, exhibiting versatile/impressive architectures and high structural flexibility. In acidified and reduced aqueous environments, isopolymolybdates generate precisely organizable building blocks, which enable unique nanoscopic molecular systems (MBs) to be constructed and further fine-tuned by hetero elements such as lanthanide (Ln) ions. This Review discusses wheel-shaped MB-based structure types with strong emphasis on the ∼30 Ln-containing MBs as of August 2021, which include both organically hybridized and nonhybridized structures synthesized to date. The spotlight is thereby put on the lanthanide ions and ligand types, which are crucial for the resulting Ln-patterns and alterations in the gigantic structures. Several critical steps and reaction conditions in their synthesis are highlighted, as well as appropriate methods to investigate them both in solid state and in solution. The final section addresses the homogeneous/heterogeneous catalytic, molecular recognition and separation properties of wheel-shaped Ln-MBs, emphasizing their inimitable behavior and encouraging their application in these areas.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.