ArticleAngewandte Chemie (International ed. in English)2022
Ligand-Enabled Disproportionation of 1,2-Diphenylhydrazine at a P
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Controlling the Redox Speciation of N,C,N-Bi Complexes Using the Anion Coordination Index.Organometallics · 2026Article
- Ambiphilic Reactivity and Switchable Methyl Transfer at a T-Shaped Bi(NNN) Complex Enabled by a Redox-Active Pincer Ligand.Journal of the American Chemical Society · 2026Article
- Isolation of a Square Pyramidal Bis(amidophenolate)-Supported As(III)-Cation: Coordination-Induced Electromerism at As.Angewandte Chemie (International ed. in English) · 2025Article
- Pd-catalyzed dehydrogenative arylation of arylhydrazines to access non-symmetric azobenzenes, including tetra-Beilstein journal of organic chemistry · 2025Article
- Highlights from the 57th Bürgenstock Conference on Stereochemistry 2024.Chemical science · 2024Article
- Metal Complexes of Redox Non-Innocent LigandMolecules (Basel, Switzerland) · 2024Review
- Calix[4]pyrrolato-germane-(thf)Journal of the American Chemical Society · 2023Article
- Metallomimetic Chemistry of a Cationic, Geometrically Constrained Phosphine in the Catalytic Hydrodefluorination and Amination of Ar-F Bonds.Journal of the American Chemical Society · 2023Article
- Are ArOrganometallics · 2023Article
- Bis(amidophenolato)phosphonium: Si-H Hydride Abstraction and Phosphorus-Ligand Cooperative Activation of C-C Multiple Bonds.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Ligand-Enabled Disproportionation of 1,2-Diphenylhydrazine at a PAngewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
We present herein the synthesis of a nearly square-pyramidal chlorophosphorane supported by the tetradentate bis(amidophenolate) ligand, N,N'-bis(3,5-di-tert-butyl-2-phenoxy)-1,2-phenylenediamide. After chloride abstraction the resulting phosphonium cation efficiently promotes the disproportionation of 1,2-diphenylhydrazine to aniline and azobenzene. Mechanistic studies, spectroscopic analyses and theoretical calculations suggest that this unprecedented reactivity mode for P
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