ArticleAngewandte Chemie (International ed. in English)2022
A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability.
Article in Angewandte Chemie (International ed. in English), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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11 citing papers in PubMed.
- Synthesis and Reactivity of Boron Triflate and Bistriflimide Complexes Bearing TwoInorganic chemistry · 2026Article
- Bridging Lewis acidic antimony centers with electron-withdrawing carborane cages.Chemical science · 2026Article
- Stepwise B[triple bond, length as m-dash]N bond cleavage by isocyanides: access to the 3-azaborole structural motif.Chemical science · 2026Article
- Reactions of 1,4-Diborinine Derivatives with COChemphyschem : a European journal of chemical physics and physical chemistry · 2025Article
- Conversion of Bestmann Ylide into Carbophosphinocarbene.Angewandte Chemie (International ed. in English) · 2025Article
- An Electrochemical Strategy for Chalcogenation ofInorganic chemistry · 2025Article
- Avenue to novelChemical science · 2024Article
- Photocatalytic Boryl Radicals Triggered Sequential B─N/C─N Bond Formation to Assemble Boron-Handled Pyrazoles.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Boosting Ring Strain and Lewis Acidity of Borirane: Synthesis, Reactivity and Density Functional Theory Studies of an Uncoordinated Arylborirane Fused to o-Carborane.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Tris(ortho-carboranyl)borane: An Isolable, Halogen-Free, Lewis Superacid.Angewandte Chemie (International ed. in English) · 2022Article
- A Three-Dimensional Inorganic Analogue of 9,10-Diazido-9,10-Diboraanthracene: A Lewis Superacidic Azido Borane with Reactivity and Stability.Angewandte Chemie (International ed. in English) · 2022Article
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4 authors.
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Abstract
Herein, we report the facile synthesis of a three-dimensional (3D) inorganic analogue of 9,10-diazido-9,10-dihydrodiboraantracene, which turned out to be a monomer in both the solid and solution state, and thermally stable up to 230 °C, representing a rare example of azido borane with boosted Lewis acidity and stability in one. Apart from the classical acid-base and Staudinger reactions, E-H bond activation (E=B, Si, Ge) was investigated. While the reaction with B-H (9-borabicyclo[3.3.1]nonane) led directly to the 1,1-addition on N
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