ArticleRSC advances2022
Conversion of bio-carbohydrates to 5-hydroxymethylfurfural in three-component deep eutectic solvent.
Article in RSC advances, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed, 17 citations in OpenAlex.
- Hydrogen Bond Acceptors Dramatically Promote Fructose Dehydration and Stability of Furanics Like 5-Hydroxymethylfurfural.International journal of molecular sciences · 2026Article
- A Simple One-Pot Synthesis of a Sulfonated Carbon/Silica Composite Catalyst from Low Value Molasses for 5‑HMF Production.ACS omega · 2026Article
- Switchable product selectivity in dehydration ofiScience · 2023Article
Corrections and comments
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Authors and funding
4 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
5-Hydroxymethylfurfural (HMF) is a valuable platform chemical derived from biomass and lots of research focuses on the synthesis of HMF from fructose and glucose. Herein, conversion of bio-carbohydrates to 5-hydroxymethylfurfural (HMF) was studied in the three-component deep eutectic solvent (DES) system, which was composed of choline chloride (ChCl), boric acid and substrates such as fructose, glucose and sucrose. Bio-carbohydrates handled under typical reaction conditions gave satisfactory conversion (44% for fructose and 31% for glucose) and yield of HMF (35% for fructose and 21% for glucose) in 1 h. Moreover, owing to the benefits of DES, the initial substrate content could be higher and the reaction temperature could be reduced, thus side reactions were effectively avoided and the selectivity of HMF was better (ranging from 79% to 100% for fructose and from 65% to 100% for glucose). We believe this method could provide a promising alternative for conversion of bio-carbohydrates to HMF and a better utilization of biomass.
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Registered trials
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