ArticleChemistry (Weinheim an der Bergstrasse, Germany)2022
[2+3] Amide Cages by Oxidation of [2+3] Imine Cages - Revisiting Molecular Hosts for Highly Efficient Nitrate Binding.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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13 citing papers in PubMed, 45 citations in OpenAlex.
- Guest-Dependent Fluorescence Response by a Highly Emissive s-Tetrazine PdChemistry, an Asian journal · 2026Article
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- Low Symmetry Cage Complexes Formed by Metalation of Symmetric Hexa-Cationic Organic Cages.Angewandte Chemie (International ed. in English) · 2025Article
- A Synthetic Lectin for Glucuronate.ACS central science · 2025Article
- Probing the Reversible Binding of Anionic Reactive Sulfur and Nitrogen Species in Imidazolium Receptors with Directional C-H Hydrogen Bonds.Inorganic chemistry · 2025Article
- Spherical Amides withMolecules (Basel, Switzerland) · 2025Article
- Beyond symmetric self-assembly and effective molarity: unlocking functional enzyme mimics with robust organic cages.Beilstein journal of organic chemistry · 2025Article
- Enzyme-like Acyl Transfer Catalysis in a Bifunctional Organic Cage.Journal of the American Chemical Society · 2024Article
- Programmable synthesis of organic cages with reduced symmetry.Chemical science · 2024Article
- Dynamic covalent synthesis.Chemical science · 2024Review
- Supramolecular Enhancement of Electrochemical Nitrate Reduction Catalyzed by Cobalt Porphyrin Organic Cages for Ammonia Electrosynthesis in Water.Angewandte Chemie (International ed. in English) · 2023Article
- Crystalline Nanoparticles of Water-Soluble Covalent Basket Cages (CBCs) for Encapsulation of Anticancer Drugs.Angewandte Chemie (International ed. in English) · 2023Article
- [2+3] Amide Cages by Oxidation of [2+3] Imine Cages - Revisiting Molecular Hosts for Highly Efficient Nitrate Binding.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
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7 authors at 1 institution in 1 country.
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Abstract
The pollution of groundwater with nitrate is a serious issue because nitrate can cause several diseases such as methemoglobinemia or cancer. Therefore, selective removal of nitrate by efficient binding to supramolecular hosts is highly desired. Here we describe how to make [2+3] amide cages in very high to quantitative yields by applying an optimized Pinnick oxidation protocol for the conversion of corresponding imine cages. By NMR titration experiments of the eight different [2+3] amide cages with nitrate, chloride and hydrogen sulfate we identified one cage with an unprecedented high selectivity towards nitrate binding vs. chloride (S=705) or hydrogensulfate (S>13500) in CD
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