ArticleChemical science2022
Zwitterionic iodonium species afford halogen bond-based porous organic frameworks.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Increasing connectivity through self-complementarity enables permanent porosity in a halogen-bonded organic framework.Chemical science · 2026Article
- Self-Complementary Dimers Based on Zwitterionic Halogen Bond Donors.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Synthesis, Structure, and Reactivity of Hypervalent Iodine Reagents Stabilized by Internal Out-of-Plane Halogen Bonding:The Journal of organic chemistry · 2026Article
- Conversion Between 2- and 3-Dimensional Halogen-Bonded Networks Formed From a Single N-Oxide/Iodoalkyne Building Block.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Benefits of Categorizing Noncovalent Bonds Based on Hydrogen, Halogen, Chalcogen, and Pnictogen Bonds.Angewandte Chemie (International ed. in English) · 2026Article
- Porous Organic Frameworks Utilizing Halogen···Halogen Interactions of X4-tetra[2,3]Thienylene (X = Br, I): Guest Dynamics and Dielectric Response.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Recent Progress in Synthetic Applications of Hypervalent Iodine(III) Reagents.Chemical reviews · 2024Review
- Key-to-lock halogen bond-based tetragonal pyramidal association of iodonium cations with the lacune rims of beta-octamolybdate.Chemical science · 2024Article
- Hybrid 2D Supramolecular Organic Frameworks (SOFs) Assembled by the Cooperative Action of Hydrogen and Halogen Bonding and π⋯π Stacking Interactions.International journal of molecular sciences · 2024Article
- Halogen Bond-Involving Self-Assembly of Iodonium Carboxylates: Adding a Dimension to Supramolecular Architecture.International journal of molecular sciences · 2023Article
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Authors and funding
14 authors.
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Abstract
Porous architectures characterized by parallel channels arranged in honeycomb or rectangular patterns are identified in two polymorphic crystals of a zwitterionic 4-(aryliodonio)-benzenesulfonate. The channels are filled with disordered water molecules which can be reversibly removed on heating. Consistent with the remarkable strength and directionality of the halogen bonds (XBs) driving the crystal packing formation, the porous structure is stable and fully preserved on almost quantitative removal and readsorption of water. The porous systems described here are the first reported cases of one-component 3D organic frameworks whose assembly is driven by XB only (XOFs). These systems are a proof of concept for the ability of zwitterionic aryliodonium tectons in affording robust one-component 3D XOFs. The high directionality and strength of the XBs formed by these zwitterions and the geometrical constraints resulting from the tendency of their hypervalent iodine atoms to act as bidentate XB donors might be key factors in determining this ability.
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