ArticleChemical science2022
Geometrically constrained square pyramidal phosphoranide.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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13 citing papers in PubMed, 28 citations in OpenAlex.
- Isolation and Reactivity of a Square-Planar Trisamido Silane.Angewandte Chemie (International ed. in English) · 2026Article
- Photochemical activation of pincer-ligated phosphoranides: mechanistic insight for reduction of aryl halides.Chemical science · 2026Article
- Direct OJACS Au · 2025Article
- Isolation of a Square Pyramidal Bis(amidophenolate)-Supported As(III)-Cation: Coordination-Induced Electromerism at As.Angewandte Chemie (International ed. in English) · 2025Article
- Phosphorus-Nitrogen Heterocycles Derived from Chelating N-Donor Ligands: Historical Advances, Recent Highlights, and Outlook.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Metal Complexes of Redox Non-Innocent LigandMolecules (Basel, Switzerland) · 2024Review
- Calix[4]pyrrolato-germane-(thf)Journal of the American Chemical Society · 2023Article
- Reactivity of a Strictly T-Shaped Phosphine Ligated by an Acridane Derived NNN Pincer Ligand.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Metallomimetic Chemistry of a Cationic, Geometrically Constrained Phosphine in the Catalytic Hydrodefluorination and Amination of Ar-F Bonds.Journal of the American Chemical Society · 2023Article
- Are ArOrganometallics · 2023Article
- Bis(amidophenolato)phosphonium: Si-H Hydride Abstraction and Phosphorus-Ligand Cooperative Activation of C-C Multiple Bonds.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Dual Reactivity of a Geometrically Constrained Phosphenium Cation.Angewandte Chemie (International ed. in English) · 2022Article
- Ligand-Enabled Disproportionation of 1,2-Diphenylhydrazine at a PAngewandte Chemie (International ed. in English) · 2022Article
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Authors and funding
7 authors at 2 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Geometrical constriction of main group elements leading to a change in the reactivity of these main group centers has recently become an important tool in main group chemistry. A lot of focus on using this modern method is dedicated to group 15 elements and especially to phosphorus. In this work, we present the synthesis, isolation and preliminary reactivity study of the geometrically constrained, square pyramidal (SP) phosphoranide anion (1
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