ArticleChemical science2022
A dysprosium single molecule magnet outperforming current pseudocontact shift agents.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Ln-M4B3T-DOTA - a new sterically overcrowded LCT for protein pseudocontact shift NMR spectroscopy.Chemical communications (Cambridge, England) · 2026Article
- The fine effects of high magnetic fields on hyperfine shifts.Chemical science · 2026Article
- Article
- Controlling Magnetic Anisotropy of Endohedral Lanthanide Ions by Carbene Addition: Paramagnetic NMR, Lanthanide Luminescence, and Single-Molecule Magnetism in Adamantylidene Adducts of MScJournal of the American Chemical Society · 2025Article
- Not Just Another Crystal Field Software.Journal of computational chemistry · 2025Article
- Interaction of Cyclosporin C with DyInternational journal of molecular sciences · 2024Article
- Dinuclear Dysprosium Compounds: The Importance of Rigid Bridges.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- LnDOTA puppeteering: removing the water molecule and imposing tetragonal symmetry.Chemical science · 2023Article
- Zero-Field SMM Behavior Triggered by Magnetic Exchange Interactions and a Collinear Arrangement of Local Anisotropy Axes in a Linear CoInorganic chemistry · 2023Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A common criterion for designing performant single molecule magnets and pseudocontact shift tags is a large magnetic anisotropy. In this article we present a dysprosium complex chemically designed to exhibit strong easy-axis type magnetic anisotropy that is preserved in dichloromethane solution at room temperature. Our detailed theoretical and experimental studies on the magnetic properties allowed explaining several features typical of highly performant SMMs. Moreover, the NMR characterization shows remarkably large chemical shifts, outperforming the current state-of-the art PCS tags.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.