ArticleChemical science2022
Crystallization induced room-temperature phosphorescence and chiral photoluminescence properties of phosphoramides.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Oxygen-responsive high-efficiency orange-red room-temperature phosphorescence from chalcogen-containing dibenzo[Chemical science · 2026Article
- Axial chirality-induced rigidification in aminoboranes enhances persistent room-temperature phosphorescence and circularly polarized luminescence.Communications chemistry · 2025Article
- Organic Room Temperature Phosphorescence from BN-Substituted Xanthene Derivatives.Angewandte Chemie (International ed. in English) · 2025Article
- Molecular design and functional outcomes of RTP and TADF traits in isomers.RSC advances · 2024Article
- Surface coating induced room-temperature phosphorescence in flexible organic single crystals.Chemical science · 2024Article
- Enabling robust blue circularly polarized organic afterglow through self-confining isolated chiral chromophore.Nature communications · 2024Article
- Simultaneously enhancing organic phosphorescence quantum yields and lifetimes for triphenylphosphine salt doped polymer films.Chemical science · 2024Article
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Authors and funding
6 authors.
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Abstract
We report the design and synthesis of a series of room temperature phosphorescent phosphoramides TPTZPO, TPTZPS, and TPTZPSe with a donor (phenothiazine)-acceptor (P = X, X = O, S, and Se) architecture. All the compounds show structureless fluorescence with a nanosecond lifetime in dilute solutions. However, these compounds show dual fluorescence and room temperature phosphorescence (RTP) in the solid state. Both the intensity and energy of luminescence depend on the heteroatom attached to the phosphorus center. For example, compound TPTZPO with the P[double bond, length as m-dash]O unit exhibits fluorescence at a higher energy region than TPTZPS and TPTZPSe with the P[double bond, length as m-dash]S and P[double bond, length as m-dash]Se groups, respectively. Crystalline samples of TPTZPO, TPTZPS, and TPTZPSe show stronger RTP than the amorphous powder of respective compounds. Detailed steady-state, time-resolved photoluminescence and computational studies established that the
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