ArticleChemical science2022
Diastereoselective and enantioselective photoredox pinacol coupling promoted by titanium complexes with a red-absorbing organic dye.
Article in Chemical science, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Breaking the limit - synthesis and properties ofChemical science · 2026Article
- Deoxygenative phosphonation of ketones by titanium.Chemical science · 2026Article
- Methyl Viologen Lead Iodide for Photocatalytic Reductive Coupling of Aromatic Carbonyls via Proton-Coupled Electron Transfer.ACS applied materials & interfaces · 2026Article
- A Light-Driven Closed-Loop Chemical Recycling System for Polypinacols.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- A Diverse Array of Catalytic Photoredox Reactions Based on Aluminum(III)-Salen Complexes: Understanding the Enhancement of Catalytic Activity via Amine Association.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Two-photon Excitation of Bright Diaza[4]Helicenes for Isotropic and Circularly Polarized Emission.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Photoredox/Nickel-Catalyzed Diastereoselective Allylation of Aldehydes with Morita-Baylis-Hillman Adducts.ACS catalysis · 2025Article
- Low-energy photoredox catalysis.Nature reviews. Chemistry · 2025Review
- Synthesis of alcohols: streamlined C1 to CChemical science · 2024Article
- Light-Induced Access to Carbazole-1,3-dicarbonitrile: A Thermally Activated Delayed Fluorescent (TADF) Photocatalyst for Cobalt-Mediated Allylations.The Journal of organic chemistry · 2023Article
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The pinacol coupling reaction, a reductive coupling of carbonyl compounds that proceeds through the formation of ketyl radicals in the presence of an electron donor, affords the corresponding 1,2-diols in one single step. The photoredox version of this transformation has been accomplished using different organic dyes or photoactive metal complexes in the presence of sacrificial donors such as tertiary amines or Hantzsch's ester. Normally, the homo-coupling of such reactive ketyl radicals is neither diastereo- nor enantio-selective. Herein, we report a highly diastereoselective pinacol coupling reaction of aromatic aldehydes promoted by 5 mol% of the non-toxic, inexpensive and available Cp
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Registered trials
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