Evidence map›Paper›PMID 35685189›Full record

ArticleJournal of applied polymer science2021

DEVELOPMENT OF BIPHENYL MONOMERS AND ASSOCIATED CROSSLINKED POLYMERS WITH INTRAMOLECULAR PI-PI INTERACTIONS.

Rishabh A Shah, Thomas W Ostertag, Shuo Tang, Thomas D Dziubla, J Zach Hilt

Open access · greenAbstract read
In one paragraph

Article in Journal of applied polymer science, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
1.1field-weighted citation impact, top 27% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed, 24 citations in OpenAlex.

  1. Review
  2. Article
  3. Article
  4. Review
  5. Dynamic Bonds: Adaptable Timescales for Responsive Materials.Angewandte Chemie (International ed. in English) · 2022
    Review
  6. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 1 institution in 1 country.

Rishabh A ShahSuperfund Research Center, University of Kentucky, Lexington, KY 40536, USA.
Thomas W OstertagSuperfund Research Center, University of Kentucky, Lexington, KY 40536, USA.
Shuo TangSuperfund Research Center, University of Kentucky, Lexington, KY 40536, USA.
Thomas D DziublaSuperfund Research Center, University of Kentucky, Lexington, KY 40536, USA.
J Zach HiltSuperfund Research Center, University of Kentucky, Lexington, KY 40536, USA.
University of Kentucky · US

Funding

Vascular Mechanisms of PCB-Induced Brain MetastasesP42ES007380 · NIEHS · UNIVERSITY OF KENTUCKY · PI PENNELL, KELLY G · 1997 to 2024
$47.8M
NIEHS NIH HHS P42 ES007380
6 · The paper itself

Abstract

Monomers containing biphenyl moieties were employed to create two sets of covalently crosslinked polymers that displayed noncovalent interactions in their 3-dimensional network. The biphenyls (precursors) used were 2-phenylphenol, 4-phenylphenol and 4,4'-dihydroxybiphenyl, and their acrylated forms were synthesized and named as 2-phenylphenolmonoacrylate (2PPMA), 4-phenylphenolmonoacrylate (4PPMA), and 4,4'-dihydroxybiphenyldiacrylate (44BDA), respectively. These were characterized by differential scanning calorimetry (DSC), nuclear magnetic resonance (NMR) and Fourier transform infrared spectroscopy (FTIR) to confirm the successful acrylation reaction. Polymers were synthesized via free radical polymerization reactions with varying crosslinker contents, and their network properties were characterized using swelling studies and compressive modulus tests. Interestingly, swelling studies did not show the expected decreasing swelling ratio with increasing crosslinker content, while compression testing indicated the expected trend of increasing modulus with increasing crosslinking density. The unexpected swelling results are hypothesized to result from the intramolecular interactions between the biphenyl side groups that result in noncovalent crosslinks.

Identifiers

PMID35685189
PMCPMC9175776
OpenAlexW3097668516

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.