The Valence Band Structure of the [Ni(Salen)] Complex: An Ultraviolet, Soft X-ray and Resonant Photoemission Spectroscopy Study.

Petr M Korusenko, Alexandra V Koroleva, Anatoliy A Vereshchagin, Danil V Sivkov, Olga V Petrova, Oleg V Levin, Alexander S Vinogradov

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Article in International journal of molecular sciences, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

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1 citing paper in PubMed.

A Comparative XPS, UV PES, NEXAFS, and DFT Study of the Electronic Structure of the Salen Ligand in the HInternational journal of molecular sciences · 2023
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7 authors.

Petr M KorusenkoDepartment of Solid State Electronics, St. Petersburg State University, 7/9 Universitetskaya nab., 199034 Saint Petersburg, Russia.ORCID 0000-0003-3048-1821

Alexandra V KorolevaResource Center "Physical Methods of Surface Investigation", St. Petersburg State University, 7/9 Universitetskaya nab., 199034 Saint Petersburg, Russia.ORCID 0000-0002-5899-0436

Anatoliy A VereshchaginDepartment of Electrochemistry, Institute of Chemistry, St. Petersburg State University, 7/9 Universitetskaya nab., 199034 Saint Petersburg, Russia.ORCID 0000-0001-6116-4197

Danil V SivkovDepartment of Solid State Electronics, St. Petersburg State University, 7/9 Universitetskaya nab., 199034 Saint Petersburg, Russia.

Olga V PetrovaDepartment of Solid State Electronics, St. Petersburg State University, 7/9 Universitetskaya nab., 199034 Saint Petersburg, Russia.ORCID 0000-0003-0398-3113

Oleg V LevinDepartment of Electrochemistry, Institute of Chemistry, St. Petersburg State University, 7/9 Universitetskaya nab., 199034 Saint Petersburg, Russia.ORCID 0000-0002-4538-316X

Alexander S VinogradovDepartment of Solid State Electronics, St. Petersburg State University, 7/9 Universitetskaya nab., 199034 Saint Petersburg, Russia.ORCID 0000-0003-1189-660X

Funding

Russian Science Foundation 21-72-10029

6 · The paper itself

Abstract

The valence band photoemission (VB PE) spectra of the [Ni(Salen)] molecular complex were measured by ultraviolet, soft X-ray and resonant photoemission (ResPE) using photons with energies ranging from 21.2 eV to 860 eV. It was found that the Ni 3d atomic orbitals' (AOs) contributions are most significant for molecular orbitals (MOs), which are responsible for the low-energy PE band at a binding energy of 3.8 eV in the VB PE spectra. In turn, the PE bands in the binding energies range of 8-16 eV are due to the photoionization of the MOs of the [Ni(Salen)] complex with dominant contributions from C

Indexed as

PhotonsEthylenediaminesPhotoelectron SpectroscopyRadiographyX-Raysdisalicylaldehyde ethylenediamineEthylenediaminesNiN2O2 coordination center[Ni(Salen)] complex (NiO2N2C16H14)participator and spectator Auger decay processessoft X-ray and ultraviolet photoemission spectroscopyvalence band photoemission (VB PE) spectraX-ray resonant photoemission spectroscopy (ResPES)

Identifiers

PMID35682886

DOI10.3390/ijms23116207

PMCPMC9181502

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